Epitaxial Growth of Large-Scale α-Phase Antimonene.

Autor: Jaroch T; Institute of Physics, Maria Curie-Sklodowska University, 20-031 Lublin, Poland., Żurawek-Wyczesany L; Institute of Physics, Maria Curie-Sklodowska University, 20-031 Lublin, Poland., Stȩpniak-Dybala A; Institute of Physics, Maria Curie-Sklodowska University, 20-031 Lublin, Poland., Krawiec M; Institute of Physics, Maria Curie-Sklodowska University, 20-031 Lublin, Poland., Kopciuszyński M; Institute of Physics, Maria Curie-Sklodowska University, 20-031 Lublin, Poland., Dróżdż P; Institute of Physics, Maria Curie-Sklodowska University, 20-031 Lublin, Poland., Gołȩbiowski M; Institute of Physics, Maria Curie-Sklodowska University, 20-031 Lublin, Poland., Zdyb R; Institute of Physics, Maria Curie-Sklodowska University, 20-031 Lublin, Poland.
Jazyk: angličtina
Zdroj: Nano letters [Nano Lett] 2024 Oct 09; Vol. 24 (40), pp. 12469-12475. Date of Electronic Publication: 2024 Sep 24.
DOI: 10.1021/acs.nanolett.4c03277
Abstrakt: Two-dimensional materials composed of elements from the 15th group of the periodic table remain largely unexplored. The primary challenge in advancing this research is the lack of large-scale layers that would facilitate extensive studies using laterally averaging techniques and enable functionalization for the fabrication of novel electronic, optoelectronic, and spintronic devices. In this report, we present a method for synthesizing large-scale antimonene layers, on the order of cm 2 . By employing molecular beam epitaxy, we successfully grow a monolayer film of α-phase antimonene on a W(110) surface passivated with a single-atom-thick layer of Sb atoms. The formation of α phase antimonene is confirmed through scanning tunneling microscopy and low-energy electron diffraction measurements. The isolated nature of the α-phase is further evidenced in the electronic structure, with linearly dispersed bands observed through angle-resolved photoelectron spectroscopy and supported by ab initio calculations.
Databáze: MEDLINE