A semiconductor SERS sensor of corrosion-resistant PPy/GO composite film by electrochemical growth for detecting crystal violet residues in fresh fish tissue.

Autor: Peng X; College of Medicine, Guizhou University, Guiyang City, 550025, China; Guizhou Province Key Lab. for Photoelectric Technology and Application, Guizhou University, Guiyang City, 550025, China., Chen Q; Guizhou Province Key Lab. for Photoelectric Technology and Application, Guizhou University, Guiyang City, 550025, China., Li X; Guizhou Province Key Lab. for Photoelectric Technology and Application, Guizhou University, Guiyang City, 550025, China., Yang L; College of Medicine, Guizhou University, Guiyang City, 550025, China; Guizhou Province Key Lab. for Photoelectric Technology and Application, Guizhou University, Guiyang City, 550025, China., Yuan Y; College of Medicine, Guizhou University, Guiyang City, 550025, China; Guizhou Province Key Lab. for Photoelectric Technology and Application, Guizhou University, Guiyang City, 550025, China., Zuo C; Guizhou Province Key Lab. for Photoelectric Technology and Application, Guizhou University, Guiyang City, 550025, China., Zhou Z; School of Electronic Information Engineering, Guiyang University, Guiyang City, 550025, China., Bai Z; College of Medicine, Guizhou University, Guiyang City, 550025, China; Guizhou Province Key Lab. for Photoelectric Technology and Application, Guizhou University, Guiyang City, 550025, China. Electronic address: zcbai@gzu.edu.cn.
Jazyk: angličtina
Zdroj: Talanta [Talanta] 2025 Jan 01; Vol. 281, pp. 126906. Date of Electronic Publication: 2024 Sep 18.
DOI: 10.1016/j.talanta.2024.126906
Abstrakt: Crystal violet (CV) residues in Marine food have produced a severe health threat in human life. In this study, we proposed a semiconductor surface-enhanced Raman scattering (SERS) sensor of corrosion-resistant Polyaniline/Graphene oxide (PPy/GO) film by electrochemical growth method to detect CV residues in fresh fish tissue. A PPy/GO dispersion solution was one-step deposited on a stainless steel sheet surface by electrochemical polymerization process to form a PPy/GO composite film acting as a semiconductor SERS substrate. Since the substrate of PPy/GO film was mainly composed of GO sheet without other metals, it had a good corrosion resistance. The SERS enhancement factor and charge transfer intensity P CT of PPy/Go SERS substrate for CV molecules were up to 1.18 × 10 6 and 0.903, respectively. Furthermore, the limit of detection (LOD) of PPy/GO SERS substrate could reach 1.58 nM. In addition, SERS sensor of PPy/GO film could identify CV residues in fresh fish tissues, and its recovery rate was 91.8 %-107 %. This preparing method and detecting method we proposed PPy/GO SERS substrate provide a new pathway for detecting CV residues in Marine food.
Competing Interests: Declaration of competing interest We declare that we have no financial and personal relationships with other people or organizations that can inappropriately influence our work, there is no professional or other personal interest of any nature or kind in any product, service or company that could be construed as influencing the position presented in, or the review of, the manuscript entitled.
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Databáze: MEDLINE