Bio-Composite Films Based on Carboxymethyl Chitosan Incorporated with Calcium Oxide: Synthesis and Antimicrobial Activity.

Autor: Thanakkasaranee S; Division of Packaging Technology, School of Agro-Industry, Faculty of Agro-Industry, Chiang Mai University, Mae-Hea, Mueang, Chiang Mai 50100, Thailand.; Center of Excellence in Agro Bio-Circular-Green Industry, Faculty of Agro-Industry, Chiang Mai University, Chiang Mai 50100, Thailand., Rachtanapun P; Division of Packaging Technology, School of Agro-Industry, Faculty of Agro-Industry, Chiang Mai University, Mae-Hea, Mueang, Chiang Mai 50100, Thailand.; Center of Excellence in Agro Bio-Circular-Green Industry, Faculty of Agro-Industry, Chiang Mai University, Chiang Mai 50100, Thailand., Rachtanapun C; Department of Food Science and Technology, Faculty of Agro-Industry, Kasetsart University, Bangkok 10900, Thailand.; Center for Advanced Studies for Agriculture and Food, Kasetsart University, Bangkok 10900, Thailand., Kanthiya T; Division of Packaging Technology, School of Agro-Industry, Faculty of Agro-Industry, Chiang Mai University, Mae-Hea, Mueang, Chiang Mai 50100, Thailand.; Office of Research Administration, Chiang Mai University, Chiang Mai 50200, Thailand., Kasi G; Division of Packaging Technology, School of Agro-Industry, Faculty of Agro-Industry, Chiang Mai University, Mae-Hea, Mueang, Chiang Mai 50100, Thailand., Sommano SR; Center of Excellence in Agro Bio-Circular-Green Industry, Faculty of Agro-Industry, Chiang Mai University, Chiang Mai 50100, Thailand.; Department of Plant and Soil Sciences, Faculty of Agriculture, Chiang Mai University, Chiang Mai 50100, Thailand., Jantanasakulwong K; Division of Packaging Technology, School of Agro-Industry, Faculty of Agro-Industry, Chiang Mai University, Mae-Hea, Mueang, Chiang Mai 50100, Thailand.; Center of Excellence in Agro Bio-Circular-Green Industry, Faculty of Agro-Industry, Chiang Mai University, Chiang Mai 50100, Thailand., Seo J; Department of Packaging, Yonsei University, 1 Yonseidae-gil, Wonju-si 26493, Gangwon-do, Republic of Korea.
Jazyk: angličtina
Zdroj: Polymers [Polymers (Basel)] 2024 Aug 23; Vol. 16 (17). Date of Electronic Publication: 2024 Aug 23.
DOI: 10.3390/polym16172393
Abstrakt: The utilization of biopolymers incorporated with antimicrobial agents is extremely interesting in the development of environmentally friendly functional materials for food packaging and other applications. In this study, the effect of calcium oxide (CaO) on the morphological, mechanical, thermal, and hydrophilic properties as well as the antimicrobial activity of carboxymethyl chitosan (CMCH) bio-composite films was investigated. The CMCH was synthesized from shrimp chitosan through carboxymethylation, whereas the CaO was synthesized via a co-precipitation method with polyethylene glycol as a stabilizer. The CMCH-CaO bio-composite films were prepared by the addition of synthesized CaO into the synthesized CMCH using a facile solution casting method. As confirmed by XRD and SEM, the synthesized CaO has a cubic shape, with an average crystalline size of 25.84 nm. The synthesized CaO exhibited excellent antimicrobial activity against Escherichia coli ( E. coli ) and Staphylococcus aureus ( S. aureus ) (>99.9% R). The addition of CaO into CMCH improved the mechanical and hydrophobic properties of the CMCH-CaO films. However, it resulted in a slight decrease in thermal stability. Notably, the CMCH-CaO10% films exhibited exceptional antimicrobial activity against E. coli (98.8% R) and S. aureus (91.8% R). As a result, such bio-composite films can be applied as an active packaging material for fruit, vegetable, or meat products.
Databáze: MEDLINE
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