Metal-Free Polymer-Based Current Collector for High Energy Density Lithium-Metal Batteries.

Autor: Wan M; Helmholtz Institute Ulm (HIU), 89081, Ulm, Germany.; Karlsruhe Institute of Technology (KIT), 76021, Karlsruhe, Germany., Gilles R; Heinz Maier-Leibnitz Zentrum (MLZ), Technische Universität München, 85748, Garching, Germany., Vacik J; Nuclear Physics Institute, Academy of Sciences of the Czech Republic, Rez, 250 68, Czech Republic., Liu H; Department of Chemical Engineering, National Taiwan University, Taipei, 10617, Taiwan.; Advanced Research Center for Green Materials Science and Technology, National Taiwan University, Taipei, 10617, Taiwan., Wu NL; Department of Chemical Engineering, National Taiwan University, Taipei, 10617, Taiwan.; Advanced Research Center for Green Materials Science and Technology, National Taiwan University, Taipei, 10617, Taiwan., Passerini S; Helmholtz Institute Ulm (HIU), 89081, Ulm, Germany.; Karlsruhe Institute of Technology (KIT), 76021, Karlsruhe, Germany., Bresser D; Helmholtz Institute Ulm (HIU), 89081, Ulm, Germany.; Karlsruhe Institute of Technology (KIT), 76021, Karlsruhe, Germany.
Jazyk: angličtina
Zdroj: Small (Weinheim an der Bergstrasse, Germany) [Small] 2024 Nov; Vol. 20 (48), pp. e2404437. Date of Electronic Publication: 2024 Sep 13.
DOI: 10.1002/smll.202404437
Abstrakt: The energy density of lithium-metal batteries (LMBs) relies substantially on the thickness of the lithium-metal anode. However, a bare, thin lithium foil electrode is vulnerable to fragmentation due to the inhomogeneity of the lithium stripping/plating process, disrupting the electron conduction pathway along the electrode. Accordingly, the current collector is an integral part to prevent the resulting loss of electronic conductivity. However, the common use of a heavy and lithiophobic Cu current collector results in a great anode mass increase and unsatisfactory lithium plating behavior, limiting both the achievable specific energy and the cycle life of LMBs. Herein, a metal-free polymer-based current collector is reported that allows for a substantial mass reduction, while simultaneously extending the cycle life of the lithium-metal anode. The specific mass of the ultra-light, 10 µm thick polymer-based current collector is only 1.03 mg cm -2 , which is ≈11% of a 10 µm thick copper foil (8.96 mg cm -2 ). As a result, LMB cells employing this novel current collector provide a specific energy of 448 Wh kg -1 , which is almost 18% higher than that of LMBs using the copper current collector (378 Wh kg -1 ), and a greatly enhanced cycle life owing to a more homogeneous lithium deposition.
(© 2024 The Author(s). Small published by Wiley‐VCH GmbH.)
Databáze: MEDLINE
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