Preparation of Metal-Supported Nanostructured Zeolite Catalysts and their Applications in the Upgrading of Biomass-Derived Furans: Advances and Prospects.

Autor: Pornsetmetakul P; School of Energy Science and Engineering, Vidyasirimedhi Institute of Science and Technology, Rayong, 21210, Thailand., Maineawklang N; School of Energy Science and Engineering, Vidyasirimedhi Institute of Science and Technology, Rayong, 21210, Thailand., Wattanakit C; School of Energy Science and Engineering, Vidyasirimedhi Institute of Science and Technology, Rayong, 21210, Thailand.
Jazyk: angličtina
Zdroj: ChemPlusChem [Chempluschem] 2024 Sep 04, pp. e202400343. Date of Electronic Publication: 2024 Sep 04.
DOI: 10.1002/cplu.202400343
Abstrakt: The development of platform chemicals derived from biomass, in particular, 5-hydroxymethylfurfural (5-HMF) and furfural (FUR), is of crucial importance in biorefinery. Over the past decades, metal-supported nanostructured zeolites, in particular, metal-supported hierarchically porous zeolites or metal-encapsulated zeolites, have been extensively elaborated because of their multiple functionalities and superior properties, for example, shape-selectivity, (hydro)thermal stability, tunable acidity and basicity, redox properties, improved diffusion, and intimacy of multiple active sites. In this review, the effects of such properties of metal-supported nanostructured zeolites on the enhanced catalytic performances in furanic compound upgrading are discussed. In addition, the recent rational design of metal-supported nanostructured zeolites is exemplified. Consequently, the ongoing challenges for further developing metal-supported nanostructured zeolites-based catalysts and their applications in HMF and FUR upgrading are identified.
(© 2024 Wiley-VCH GmbH.)
Databáze: MEDLINE
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