| Autor: |
Aquilia S; Interdepartmental Research Unit of Peptide and Protein Chemistry and Biology, University of Florence, Via della Lastruccia 13, I-50019 Sesto Fiorentino, Italy.; Department of Chemistry 'Ugo Schiff', University of Florence, Via della Lastruccia 13, I-50019 Sesto Fiorentino, Italy.; Spin-PET S.r.l., Viale R. Piaggio 32, I-56025 Pontedera, Italy., Rosi L; Department of Chemistry 'Ugo Schiff', University of Florence, Via della Lastruccia 13, I-50019 Sesto Fiorentino, Italy., Pinna M; Spin-PET S.r.l., Viale R. Piaggio 32, I-56025 Pontedera, Italy., Bianchi S; Spin-PET S.r.l., Viale R. Piaggio 32, I-56025 Pontedera, Italy., Giurlani W; Department of Chemistry 'Ugo Schiff', University of Florence, Via della Lastruccia 13, I-50019 Sesto Fiorentino, Italy., Bonechi M; Department of Chemistry 'Ugo Schiff', University of Florence, Via della Lastruccia 13, I-50019 Sesto Fiorentino, Italy., Ciardelli F; Spin-PET S.r.l., Viale R. Piaggio 32, I-56025 Pontedera, Italy., Papini AM; Interdepartmental Research Unit of Peptide and Protein Chemistry and Biology, University of Florence, Via della Lastruccia 13, I-50019 Sesto Fiorentino, Italy.; Department of Chemistry 'Ugo Schiff', University of Florence, Via della Lastruccia 13, I-50019 Sesto Fiorentino, Italy., Bello C; Interdepartmental Research Unit of Peptide and Protein Chemistry and Biology, University of Florence, Via della Lastruccia 13, I-50019 Sesto Fiorentino, Italy.; Department of Chemistry 'Ugo Schiff', University of Florence, Via della Lastruccia 13, I-50019 Sesto Fiorentino, Italy. |
| Abstrakt: |
In recent years, there has been increasing interest in developing novel materials based on natural biopolymers as a renewable alternative to petroleum-based plastics. The availability of proteins derived from agricultural by-products, along with their favourable properties, has fostered a renewed interest in protein-based materials, promoting research in innovative technologies. In this study, we propose the use of rapeseed protein-rich meal as the main ingredient for the preparation of novel sustainable materials combining excellent environmental properties such as biodegradability and renewability. The application of sustainable products in the present high-tech society requires the modification of the basic native properties of these natural compounds. The original route proposed in this paper consists of preparation via the compression moulding of flexible biomaterials stabilized by crosslinkers/chain extenders. An investigation of the effects of different denaturing and disulfide bond reducing agents, crosslinkers, and preparation conditions on the material mechanical behaviour demonstrated that the novel materials have appreciable strength and stiffness. The results show the potential of utilizing full meal from vegetable by-products to prepare protein-based materials with guaranteed ecofriendly characteristics and mechanical properties adequate for specific structural applications. |
