| Autor: |
Fujita H; Faculty of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical, and Health Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan., Arai T; Faculty of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical, and Health Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan., Kuchiki N; Faculty of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical, and Health Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan., Kunishima M; Faculty of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical, and Health Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan.; Faculty of Pharmaceutical Sciences, Kobe Gakuin University, 1-1-3 minatojima, Chuo-ku, Kobe, Hyogo 650-8586, Japan. |
| Abstrakt: |
Ylidic nitrogen-based π-electron-donating groups, (quinuclidinio)amidyl (QA) and (1-azanorbornanio)amidyl (ANA) groups, were developed to shift the absorption of push-pull benzenes toward longer wavelengths. Changing the pyrrolidinyl group to the QA or ANA group achieved a bathochromic shift of 45-100 nm in the maximum absorption wavelength, depending on the push-pull π-conjugated system investigated ( p -nitrobenzene, 1,8-naphthalimide, and an azo dye). |
