Tetraphenylpentalenide organolanthanide complexes.

Autor: Katzer NJ; Department of Chemistry, University of California, Berkeley, CA, 94720, USA. pla@berkeley.edu.; Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA., Kaur M; Department of Chemistry, University of Bath, BA2 7AY, UK. u.hintermair@bath.ac.uk., Sen A; Department of Chemistry, University at Buffalo, State University of New York, Buffalo, NY 14260, USA. jochena@buffalo.edu., Nimaiyar R; Department of Chemistry, University of California, Berkeley, CA, 94720, USA. pla@berkeley.edu., Autschbach J; Department of Chemistry, University at Buffalo, State University of New York, Buffalo, NY 14260, USA. jochena@buffalo.edu., Arnold PL; Department of Chemistry, University of California, Berkeley, CA, 94720, USA. pla@berkeley.edu.; Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA., Hintermair U; Department of Chemistry, University of Bath, BA2 7AY, UK. u.hintermair@bath.ac.uk.
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2024 Sep 05; Vol. 60 (72), pp. 9749-9752. Date of Electronic Publication: 2024 Sep 05.
DOI: 10.1039/d4cc02570a
Abstrakt: The D 2h symmetrical 1,3,4,6-tetraphenylpentalenide is an excellent ligand for the stabilisation of strongly coloured bis(pentalenide) Ln III sandwich complexes. These easily accessible compounds complement previously reported lanthanide organometallics and provide new opportunities to understand the roles of the f-orbitals in electronic structure and bonding.
Databáze: MEDLINE