Determination of the significance of atomic concentration on surface properties of Ba x Mg 1- x F 2 alloy coatings via microscopic and spectroscopic techniques.

Autor: Baris E; Institute of Graduate Studies in Sciences, Istanbul University Istanbul Turkey ezgibbaris@gmail.com +90 212 4400000., Tanoren B; Department of Natural Sciences, Faculty of Engineering and Natural Sciences, Acibadem University Istanbul Turkey bukem.tanoren@acibadem.edu.tr +90 216 5765076 +90 216 5004156., Dipcin B; Department of Molecular Biology and Genetics, Faculty of Engineering and Natural Sciences, Acibadem University Istanbul Turkey beste.dipcin@live.acibadem.edu.tr., Guzelcimen F; Department of Physics, Faculty of Science, Istanbul University Istanbul Turkey feyzag@istanbul.edu.tr +90 212 4555766 +90 212 4555700.
Jazyk: angličtina
Zdroj: RSC advances [RSC Adv] 2024 Aug 19; Vol. 14 (36), pp. 26043-26049. Date of Electronic Publication: 2024 Aug 19 (Print Publication: 2024).
DOI: 10.1039/d4ra05211k
Abstrakt: Both BaF 2 and MgF 2 compounds and Ba x Mg 1- x F 2 alloy thin films were deposited on glass and silicon (Si) substrates in nanometric sizes (100 ± 10 nm) in a high vacuum environment by radio frequency (rf) magnetron sputtering. Using BaF 2 (99% purity) and MgF 2 (99% purity) target materials and adjusting the power levels applied to these targets, Ba x Mg 1- x F 2 alloy coatings at different atomic concentrations were formed under the same vacuum conditions. The microstructure and surface characteristics of the samples were analysed with the help of spectroscopic and microscopic methods. For the surface characterization, with scanning acoustic microscopy (SAM), 2-dimensional surface acoustic images of the samples were mapped, the surface acoustic impedance values were determined, and information about the micro hardness of the materials was obtained. Surface roughness values and grain sizes were obtained by taking 3-dimensional surface images of investigated materials using atomic force microscopy (AFM). Average nanometric particle sizes were determined for each sample with scanning electron microscopy (SEM), therefore, information about surface homogeneity was obtained. For the microstructural characterization, quantitative elemental analysis was performed using scanning electron microscopy/energy dispersive X-ray spectroscopy (SEM-EDS), and stoichiometric ratios of atomic compositions were identified. By evaluating the data obtained from the microscopic and spectroscopic measurements, the effect of the atomic concentration parameter on the morphological properties of the material was determined. The usability of the produced binary fluoride alloy thin film coatings is promising for emerging optoelectronic, ceramic industry, biomedical and surface acoustic wave applications.
Competing Interests: There are no conflicts to declare.
(This journal is © The Royal Society of Chemistry.)
Databáze: MEDLINE