Innovating Ferro-sonication approach for extracting microplastics from wastewater.

Autor: Mathew J; Department of Civil Engineering, Lassonde School of Engineering, York University, Toronto, Canada., Bhardwaj G; Department of Civil Engineering, Lassonde School of Engineering, York University, Toronto, Canada., Pulicharla R; Department of Civil Engineering, Lassonde School of Engineering, York University, Toronto, Canada., Rezai P; Department of Mechanical Engineering, Lassonde School of Engineering, York University, Toronto, Canada. Electronic address: prezai@yorku.ca., Brar SK; Department of Civil Engineering, Lassonde School of Engineering, York University, Toronto, Canada. Electronic address: satinder.brar@lassonde.yorku.ca.
Jazyk: angličtina
Zdroj: The Science of the total environment [Sci Total Environ] 2024 Nov 15; Vol. 951, pp. 175595. Date of Electronic Publication: 2024 Aug 16.
DOI: 10.1016/j.scitotenv.2024.175595
Abstrakt: For accurate and reliable analysis of microplastics (MPs) in wastewater (WW), it is imperative to comprehend the significance of pre-treating WW before analysis. The suspended solids (SS) in the matrix tend to adhere to the MPs during filtration, which interferes with the detection of the MPs. In this regard, the present study aims to develop and optimize a pretreatment method to improve the extraction efficiency of MPs from WW by reducing the SS. A combination of the Fenton reaction and ultrasonication, ferro-sonication (Fe-UlS), was proposed to digest and eliminate the SS from WW. This hybrid pretreatment, Fe-UlS, was optimized for ultrasonication amplitude, treatment time, and hydrogen peroxide dose using response surface methodology (RSM) with a Box-Behnken design, achieving a desirability of 0.984. The optimum conditions for the Fe-UlS, such as the (1:1) Fenton reagent ratio (0.05 M FeSO 4 : 30 % H 2 O 2 ), ultrasonication amplitude (31 %), and total process time (30 min) were found to be statistically significant (p < 0.05). The developed method was then employed for the extraction of spiked polyethylene (PE), polypropylene (PP) and polyethylene terephthalate (PET) MPs in real WW and found efficient in removing 83 % of the TSS present in the primary influent were in 30 min at a temperature of 45 °C. Also, the method did not affect the physio-chemical characteristics of the MPs; however, the thermal analysis of PE and PP MPs showed a statistically significant decrease in the melting temperature, as proven by paired t-test analysis. Further, a non-targeted liquid chromatography-mass spectrometry (LC-MS) analysis proved that Fe-UlS is a stable process, as it did not cause any leaching of MPs under the optimum pretreatment conditions. Finally, Laser Direct-Infrared Imaging (LD-IR) analysis was conducted to validate the developed Fe-UlS pretreatment approach for MP analysis in real WW. About 3434 MPs were detected in 100 mL of WW primary influent, within the size range of 9 to 500 μm. This hybrid pretreatment approach not only streamlines WW sample processing but also reduces the required concentration of Fenton reagent and processing time, yielding accurate and reliable results for monitoring MPs in WW.
Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: Satinder Kaur Brar reports financial support was provided by Natural Sciences and Engineering Research Council of Canada. Satinder Kaur Brar reports financial support was provided by James and Joanne Love Chair in Environmental Engineering. If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
(Copyright © 2024 The Authors. Published by Elsevier B.V. All rights reserved.)
Databáze: MEDLINE
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