Sieving-type Electric Double Layer with Hydrogen Bond Interlocking to Stable Zinc Metal Anode.

Autor: Yan T; South China University of Technology, School of Chemistry and Chemical Engineering, CHINA., Wu B; South China University of Technology, School of Chemistry and Chemical Engineering, CHINA., Liu S; South China University of Technology, School of Chemistry and Chemical Engineering, CHINA., Tao M; South China University of Technology, School of Chemistry and Chemical Engineering, CHINA., Liang J; South China University of Technology, School of Chemistry and Chemical Engineering, CHINA., Li M; South China University of Technology, School of Chemistry and Chemical Engineering, CHINA., Xiang C; South China University of Technology, School of Chemistry and Chemical Engineering, CHINA., Cui Z; South China University of Technology, School of Chemistry and Chemical Engineering, CHINA., Du L; South China University of Technology, School of Chemistry and Chemical Engineering, CHINA., Liang Z; South China University of Technology, School of Chemistry and Chemical Engineering, CHINA., Song H; South China University of Technology, School of Chemistry and Chemical Engineering, 381 Wushan Road, Tianhe District, Guangzhou, P.R. China, 510641, 510641, Guangzhou, CHINA.
Jazyk: angličtina
Zdroj: Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2024 Aug 15, pp. e202411470. Date of Electronic Publication: 2024 Aug 15.
DOI: 10.1002/anie.202411470
Abstrakt: The stability of aqueous zinc metal batteries is significantly affected by side reactions and dendrite growth on the anode interface, which primarily originate from water and anions. Herein, we introduce a multi H-bond site additive, 2, 2'-Sulfonyldiethanol (SDE), into an aqueous electrolyte to construct a sieving-type electric double layer (EDL) by hydrogen bond interlock in order to address these issues. On the one hand, SDE replaces H2O and SO42- anions that are adsorbed on the zinc anode surface, expelling H2O/SO42- from the EDL and thereby reducing the content of H2O/SO42- at the interface. On the other hand, when Zn2+ are de-solvated at the interface during the plating, the strong hydrogen bond interaction between SDE and H2O/SO42- can trap H2O/SO42- from the EDL, further decreasing their content at the interface. This effectively sieves them out of the zinc anode interface and inhibits the side reactions. Moreover, the unique characteristics of trapped SO42- anions can restrict their diffusion, thereby enhancing the transference number of Zn2+ and promoting dendrite-free deposition and growth of Zn. Consequently, utilizing an SDE/ZnSO4 electrolyte enables excellent cycling stability in Zn//Zn symmetrical cells and Zn//MnO2 full cells with lifespans exceeding 3500 h and 2500 cycles respectively.
(© 2024 Wiley‐VCH GmbH.)
Databáze: MEDLINE
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