Dual, Photo-Responsive and Redox-Active Supramolecular Foldamers.

Autor: Davis AR; School of Chemistry, University of Birmingham, Edgbaston, Birmingham, B15 2TT, UK., Dismorr JO; School of Chemistry, University of Birmingham, Edgbaston, Birmingham, B15 2TT, UK., Male L; School of Chemistry, University of Birmingham, Edgbaston, Birmingham, B15 2TT, UK., Tucker JHR; School of Chemistry, University of Birmingham, Edgbaston, Birmingham, B15 2TT, UK., Pike SJ; School of Chemistry, University of Birmingham, Edgbaston, Birmingham, B15 2TT, UK.
Jazyk: angličtina
Zdroj: Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2024 Nov 07; Vol. 30 (62), pp. e202402423. Date of Electronic Publication: 2024 Oct 16.
DOI: 10.1002/chem.202402423
Abstrakt: We report on dual, light-responsive and redox-active foldamers that demonstrate reversible and robust stimuli-induced behaviour. Herein, UV/Vis, 1 H NMR and circular dichroism (CD) spectroscopy and cyclic voltammetry have been used to establish the reversibility and highly robust nature of the light- and redox-driven behaviour of these new foldamers with minimal levels of fatigue observed even upon multiple cyclic treatments with irradiative/non-irradiative and oxidative/reductive conditions. This proof-of-concept work paves the way towards the creation of novel stimuli-responsive foldamers of increasing sophistication capable of demonstrating reversible and robust responses to multiple distinct stimuli.
(© 2024 The Author(s). Chemistry - A European Journal published by Wiley-VCH GmbH.)
Databáze: MEDLINE
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