| Autor: |
Gerasimov MA; Department of Chemistry, Lomonosov Moscow State University, Moscow 119991, Russia., Matveev PI; Department of Chemistry, Lomonosov Moscow State University, Moscow 119991, Russia., Evsiunina MV; Department of Chemistry, Lomonosov Moscow State University, Moscow 119991, Russia., Khult EK; Department of Materials Science, Lomonosov Moscow State University, Moscow 119991, Russia., Kalle P; N.S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Moscow 119991, Russia., Petrov VS; Department of Chemistry, Lomonosov Moscow State University, Moscow 119991, Russia., Lemport PS; Department of Chemistry, Lomonosov Moscow State University, Moscow 119991, Russia., Petrov VG; Department of Chemistry, Lomonosov Moscow State University, Moscow 119991, Russia., Kostikova GV; Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences, Moscow 119071, Russia., Ustynyuk YA; Department of Chemistry, Lomonosov Moscow State University, Moscow 119991, Russia., Nenajdenko VG; Department of Chemistry, Lomonosov Moscow State University, Moscow 119991, Russia. |
| Abstrakt: |
A systematic study of extraction systems for the separation of f -elements using the tetradentate N,O-donor diamide of 1,10-phenanthroline-2,9-dicarboxylic acid ( L ) in various molecular and ionic solvents was performed. It was demonstrated that the nature of a diluent has a significant impact on solvent extraction of Am(III) and Ln(III) and the stoichiometry of formed complexes with f -elements. The mechanism of complexation and forms of complexes in different diluents were investigated by radiometric methods, UV-vis titration, and XRD. |
