| Autor: |
Wesner A; Institute of Technical and Macromolecular Chemistry, University of Hamburg, Bundesstraße 45, 20146 Hamburg, Germany., Papajewski MP; Institute of Technical and Macromolecular Chemistry, University of Hamburg, Bundesstraße 45, 20146 Hamburg, Germany., Schidowski L; Institute of Technical and Macromolecular Chemistry, University of Hamburg, Bundesstraße 45, 20146 Hamburg, Germany., Ruhmlieb C; Institute of Physical Chemistry, University of Hamburg, Grindelallee 117, 20146 Hamburg, Germany. jakob.albert@uni-hamburg.de., Poller MJ; Institute of Technical and Macromolecular Chemistry, University of Hamburg, Bundesstraße 45, 20146 Hamburg, Germany., Albert J; Institute of Technical and Macromolecular Chemistry, University of Hamburg, Bundesstraße 45, 20146 Hamburg, Germany. |
| Abstrakt: |
Polyoxometalates (POMs), in particular the Keggin-type HPA-5 (H 8 PV 5 Mo 7 O 40 ) are widely established as effective catalysts for acid- and redox-catalyzed reactions. Yet, they are mainly used as homogeneous catalysts, which poses challenges regarding catalyst separation. This study explores the synthesis of supported HPA-5, and its application as a heterogeneous catalyst for biomass conversion, focusing on activated carbons with diverse chemical and physical properties as support materials. Characterization of these carbons gives insights into the influence of surface area, oxygen content, and acidity on HPA adsorption and stability. Activated carbon CW20, was found to be the best support due to its high vanadium loading and effective preservation of the HPA-5 structure. It underwent various pre- and post-treatments, and the obtained supported catalysts were evaluated for their catalytic performance in converting glucose under both oxidative (OxFA process) and inert (Retro-Aldol condensation) conditions. Notably, HPA-5 supported on CW20 emerged as an exceptional catalyst for the retro-aldol condensation of glucose to lactic acid, achieving a selectivity of 15% and a conversion rate of 71%, with only minimal vanadium leaching. |
