Sustainable, aqueous exfoliation of MoS 2 via bio-inspired avenues.

Autor: Pham LN; Institute for Frontier Materials, Deakin University, Geelong 3216 VIC, Australia. tiffany.walsh@deakin.edu.au., Perdomo Y; Department of Chemistry, University of Miami, Coral Gables, FL 33146, USA. knecht@miami.edu., Slocik JM; Air Force Research Laboratory, Wright-Patterson Air Force Base, Ohio 45433, USA., Rao R; Air Force Research Laboratory, Wright-Patterson Air Force Base, Ohio 45433, USA., Walsh TR; Institute for Frontier Materials, Deakin University, Geelong 3216 VIC, Australia. tiffany.walsh@deakin.edu.au., Knecht MR; Department of Chemistry, University of Miami, Coral Gables, FL 33146, USA. knecht@miami.edu.; Dr. JT Macdonald Foundation Biomedical Nanotechnology Institute, University of Miami, Miami, FL 33136, USA.
Jazyk: angličtina
Zdroj: Journal of materials chemistry. B [J Mater Chem B] 2024 Sep 11; Vol. 12 (35), pp. 8662-8671. Date of Electronic Publication: 2024 Sep 11.
DOI: 10.1039/d4tb01127a
Abstrakt: Two dimensional (2D) nanosheets of MoS 2 were succesfully produced by an exfoliation process in aqueous media with the support from peptides and sonication. The exfoliation process assisted by uncapped MoSBP1 peptides was found to have enhanced efficiency in comparison to the capped counterpart. MoS 2 nanosheets obtained using uncapped MoSBP1 have thinner structures containing one layer of MoS 2 , while in capped version of peptides, MoS 2 nanosheets tend to form multilayer (up to 4) structures of exfoliated sheets. Molecular dynamics simulations indicate that inter-sheet gaps generated by sonication in MoS 2 nanostacks cannot be maintained by water only; the gaps closed after ∼11 ns. Both capped CMoSBP1 and uncapped MoSBP1 were seen to spontaneously insert into the gap in nanostacks of MoS 2 and they can ultimately maintain the inter-sheet gap for longer (≥20 ns). Potential of mean force profiles for the association of two MoS 2 nanosheets decorated with CMoSBP1 and MoSBP1 versions of peptides revealed that uncapped MoSBP1 peptides provide good protection from MoS 2 nanosheet re-unification. Such protection can prevent the nanosheets from reassociation and subsequent aggregation, whereas the capped CMoSBP1 peptides can offer protection, but over a shorter range. These simulation results could explain the experimental observation of greater efficiency of exfoliation in uncapped MoSBP1 peptides.
Databáze: MEDLINE
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