InCl 3 catalyzed simultaneous reductive sulfoximination and O -silylation: synthesis of silyloxy benzylsulfoximine.

Autor:	Natarajan K; Department of Chemistry, National Institute of Technology - Tiruchirappalli, 620015, Tamil Nadu, India. ganeshnandi@gmail.com., Jayakumar V; Department of Chemistry, School of Advanced Sciences, Vellore Institute of Technology, Katpadi, 632014 Vellore, Tamil Nadu, India., Padma Priya VR; Department of Chemistry, National Institute of Technology - Tiruchirappalli, 620015, Tamil Nadu, India. ganeshnandi@gmail.com., Mercy AAH; Department of Chemistry, National Institute of Technology - Tiruchirappalli, 620015, Tamil Nadu, India. ganeshnandi@gmail.com., Nandi GC; Department of Chemistry, National Institute of Technology - Tiruchirappalli, 620015, Tamil Nadu, India. ganeshnandi@gmail.com.
Jazyk:	angličtina
Zdroj:	Organic & biomolecular chemistry [Org Biomol Chem] 2024 Aug 22; Vol. 22 (33), pp. 6699-6702. Date of Electronic Publication: 2024 Aug 22.
DOI:	10.1039/d4ob00713a
Abstrakt:	This article describes the synthesis of ortho -silyloxy benzylsulfoximine via the reaction of salicylaldehyde and sulfoximine in the presence of silane and InCl 3 . The steps include simultaneous reductive sulfoximination and an O -silylation process. To the best of our knowledge, this is the first report of this kind of reaction, where both reductive amination (here sulfoximination) and O -silylation occur concurrently.
Databáze:	MEDLINE
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