| Autor: |
Alikhani M; Department of Chemistry, Payame Noor University Tehran Iran., Khoshkalam E; Department of Soil Science, Faculty of Agriculture, Ferdowsi University of Mashhad (FUM) Mashhad Iran e.khoshkalam@alumni.um.ac.ir +985138807147 +989104050217., Sadeghi J; Department of Soil Science, Faculty of Agriculture, Ferdowsi University of Mashhad (FUM) Mashhad Iran e.khoshkalam@alumni.um.ac.ir +985138807147 +989104050217., Bulgariu L; Department of Environmental Engineering and Management, Cristofor Simionescu Faculty of Chemical Engineering and Environmental Protection, Gheorghe Asachi Technical University of Iasi 700050 Iasi Romania., Eshghi H; Department of Chemistry, Faculty of Science, Ferdowsi University of Mashhad (FUM) Mashhad Iran. |
| Abstrakt: |
The primary goal of this study is to examine PO 4 3- adsorption from aqueous solutions using zinc-doped carbon dots (Zn-N-CDs) as a new adsorbent and cost-effective technique. Zn-N-CDs were produced through a hydrothermal process and subsequently identified using various techniques. The effect of reaction time, temperature, pH, ionic strength, adsorbent dosage, initial PO 4 3- concentration, and anion competition (NO 3 - , Cl - , HCO 3 - , and SO 4 2- ) on PO 4 3- adsorption using Zn-N-CDs were investigated. The characterization results depicted that Zn-N-CDs have a spherical structure without obvious aggregation and revealed the amorphous nature of carbon dots with many pores. Zn-N-CDs had a high affinity for adsorbing PO 4 3- , reaching equilibrium within 5 minutes. While PO 4 3- adsorption reduced with an increase in temperature, it increased with pH and ionic strength. The optimal conditions for PO 4 3- adsorption were determined to be pH 8, 100 mM KCl as an ionic strength, and 5 g L -1 of Zn-N-CDs. The presence of SO 4 2- and HCO 3 - as competing anions slightly decreased PO 4 3- adsorption. Thermodynamic studies revealed that PO 4 3- adsorption onto Zn-N-CDs was endothermic, spontaneous, and disordered, as evidenced by Δ G ° < 0, Δ H ° > 0, and Δ S ° > 0. The experimental data fit well with a pseudo-second-order kinetic model ( R 2 = 0.999) and the Freundlich isotherm model ( R 2 = 0.9754), signifying that PO 4 3- adsorption onto Zn-N-CDs occurs through multi-layer and chemi-sorption mechanisms. Overall, Zn-N-CDs indicated a great capability to adsorb high concentrations of PO 4 3- across a wide range of pH values, indicating their potential for environmental remediation.
Competing Interests: The authors declare no conflict of interest.
(This journal is © The Royal Society of Chemistry.) |
