| Autor: |
Tickner BJ; Centre for Hyperpolarisation in Magnetic Resonance, University of York, Heslington, United Kingdom, YO10 5NY., Gammons R; Department of Chemistry, University of York, Heslington, United Kingdom, YO10, 5DD., Whitwood AC; Department of Chemistry, University of York, Heslington, United Kingdom, YO10, 5DD., Duckett SB; Centre for Hyperpolarisation in Magnetic Resonance, University of York, Heslington, United Kingdom, YO10 5NY. |
| Jazyk: |
angličtina |
| Zdroj: |
Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2024 Jul 27; Vol. 80 (Pt 8), pp. 890-893. Date of Electronic Publication: 2024 Jul 27 (Print Publication: 2024). |
| DOI: |
10.1107/S2056989024007151 |
| Abstrakt: |
Single crystals of the mol-ecular compound, {Cu 20 Ir 6 Cl 8 (C 21 H 24 N 2 ) 6 (C 4 H 4 N 2 ) 3 ]·3.18CH 3 OH or [({Cu 10 Ir 3 }Cl 4 (IMes) 3 (pyrazine)) 2 (pyrazine)]·3.18CH 3 OH [where IMes is 1,3-bis-(2,4,6-trimethylphen-yl)imidazol-2-yl-idene], with a unique heterometallic cluster have been prepared and the structure revealed using single-crystal X-ray diffraction. The mol-ecule is centrosymmetric with two {Cu 10 Ir 3 } cores bridged by a pyrazine ligand. The polymetallic cluster contains three stabilizing N -heterocyclic carbenes, four Cl ligands, and a non-bridging pyrazine ligand. Notably, the Cu-Ir core is arranged in an unusual shape containing 13 vertices, 22 faces, and 32 sides. The atoms within the trideca-metallic cluster are arranged in four planes, with 2, 4, 4, 3 metals in each plane. Ir atoms are present in alternate planes with an Ir atom featuring in the peripheral bimetallic plane, and two Ir atoms featuring on opposite sides of the non-adjacent tetra-metallic plane. The crystal contains two disordered methanol solvent mol-ecules with an additional region of non-modelled electron density corrected for using the SQUEEZE routine in PLATON [Spek (2015 ▸). Acta Cryst. C 71 , 9-18]. The given chemical formula and other crystal data do not take into account the unmodelled methanol solvent mol-ecule(s).
(© Tickner et al. 2024.) |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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