Ordered assembly of two different metal clusters with the same topological connectivity in one single coordination network.

Autor: Cao JW; Key Laboratory of Special Functional and Smart Polymer Materials of Ministry of Industry and Information Technology, Xi'an Key Laboratory of Functional Organic Porous Materials, School of Chemistry and Chemical Engineering, Northwestern Polytechnical University Xi'an Shaanxi 710072 China ckjiscon@nwpu.edu.cn., Zhang T; Key Laboratory of Special Functional and Smart Polymer Materials of Ministry of Industry and Information Technology, Xi'an Key Laboratory of Functional Organic Porous Materials, School of Chemistry and Chemical Engineering, Northwestern Polytechnical University Xi'an Shaanxi 710072 China ckjiscon@nwpu.edu.cn., Chen J; Key Laboratory of Special Functional and Smart Polymer Materials of Ministry of Industry and Information Technology, Xi'an Key Laboratory of Functional Organic Porous Materials, School of Chemistry and Chemical Engineering, Northwestern Polytechnical University Xi'an Shaanxi 710072 China ckjiscon@nwpu.edu.cn., Wang JB; Key Laboratory of Special Functional and Smart Polymer Materials of Ministry of Industry and Information Technology, Xi'an Key Laboratory of Functional Organic Porous Materials, School of Chemistry and Chemical Engineering, Northwestern Polytechnical University Xi'an Shaanxi 710072 China ckjiscon@nwpu.edu.cn., Wang Y; Key Laboratory of Special Functional and Smart Polymer Materials of Ministry of Industry and Information Technology, Xi'an Key Laboratory of Functional Organic Porous Materials, School of Chemistry and Chemical Engineering, Northwestern Polytechnical University Xi'an Shaanxi 710072 China ckjiscon@nwpu.edu.cn., Chen KJ; Key Laboratory of Special Functional and Smart Polymer Materials of Ministry of Industry and Information Technology, Xi'an Key Laboratory of Functional Organic Porous Materials, School of Chemistry and Chemical Engineering, Northwestern Polytechnical University Xi'an Shaanxi 710072 China ckjiscon@nwpu.edu.cn.
Jazyk: angličtina
Zdroj: Chemical science [Chem Sci] 2024 Jun 25; Vol. 15 (30), pp. 11928-11936. Date of Electronic Publication: 2024 Jun 25 (Print Publication: 2024).
DOI: 10.1039/d4sc02550d
Abstrakt: The introduction of heterogeneous components within one single coordination network leads to the multifunctionality of the final material. However, it is hard to precisely control the local distribution of these different components in such a coordination network, especially for different components with identical topological connectivity. In this study, we successfully achieved the ordered assembly of [Mn 3 (μ 3 -O)] nodes and [Mn 6 (μ 3 -O) 2 (CH 3 COO) 3 ] nodes within one pacs coordination network. The resulting new structure (NPU-6) with heterogeneous metal nodes simultaneously inherits the advantages of both parent networks (good thermal stability and high pore volume). The significant effect of the reaction concentration of competing ligand CH 3 COO - on the mixed assembly of these two nodes in NPU-6 is revealed by a series of control experiments. This method is anticipated to offer a valuable reference for orderly assembling heterogeneous components in coordination networks.
Competing Interests: There are no conflicts to declare.
(This journal is © The Royal Society of Chemistry.)
Databáze: MEDLINE
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