| Autor: |
Guiot F; Univ. Rennes, CNRS, ISCR-UMR 6226, F-35000 Rennes, France., Prestipino C; CRISMAT, CNRS, Normandie Univ, ENSICAEN, UNICAEN, 14000 Caen, France., Guilmeau E; CRISMAT, CNRS, Normandie Univ, ENSICAEN, UNICAEN, 14000 Caen, France., Acharyya P; CRISMAT, CNRS, Normandie Univ, ENSICAEN, UNICAEN, 14000 Caen, France., Raveau B; CRISMAT, CNRS, Normandie Univ, ENSICAEN, UNICAEN, 14000 Caen, France., Fujii S; Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University, Osaka 565-0871, Japan.; Nanostructures Research Laboratory, Japan Fine Ceramics Center, Nagoya 456-8587, Japan., Yao K; Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University, Osaka 565-0871, Japan., Tran T; Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University, Osaka 565-0871, Japan., Dorcet V; Univ. Rennes, CNRS, ISCR-UMR 6226, F-35000 Rennes, France., Malaman B; Institut Jean Lamour, UMR 7198, CNRS, Université de Lorraine, 54011 Nancy, France., Schweitzer T; Institut Jean Lamour, UMR 7198, CNRS, Université de Lorraine, 54011 Nancy, France., Elkaïm E; Synchrotron SOLEIL, L'orme des Merisiers, 91192 Gif-sur-Yvette, France., Yoshiya M; Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University, Osaka 565-0871, Japan.; Nanostructures Research Laboratory, Japan Fine Ceramics Center, Nagoya 456-8587, Japan., Lemoine P; Institut Jean Lamour, UMR 7198, CNRS, Université de Lorraine, 54011 Nancy, France. |
| Abstrakt: |
Comprehending the relationship between crystal structures and transport properties is crucial to develop materials with improved electrical and thermal properties for thermoelectric applications. In this article, we report on the complex crystal structure and physical properties of Cr 2 Sn 3 S 7 , a n -type magnetic semiconductor with a low energy band gap and low thermal conductivity. Importantly, we demonstrate that the high level of structural complexity is related to the coexistence of two sublattices: a host lattice, [Cr 4 Sn 2 S 11 ] 2- , characterized by a mixed Sn 4+ /Cr 3+ occupancy of its cationic sites, and a guest lattice characterized by [Sn 4 S 3 ] 2+ chains, containing Sn 2+ cations only, closely related to the ones encountered in the orthorhombic SnS compound. By combining experiments including X-ray diffraction with ab initio calculations of electrons and phonons, we succeeded to elucidate the origin of the low thermal conductivity in Cr 2 Sn 3 S 7. We demonstrate that the low dimensionality of the [Sn 4 S 3 ] 2+ chains, which generates weak Sn···S interactions with the 3D host lattice, is induced by the lone pair stereochemical activity of Sn 2+ . This lattice softening favors strong anisotropic vibrations at low frequencies, highlighting the primordial role played by Sn 2+ cations in both crystal structure dimensionality and low thermal conductivity in tin-based sulfides. |
