| Autor: |
Teixeira FC; Laboratório Nacional de Energia e Geologia, I.P., Estrada do Paço do Lumiar, 22, 1649-038 Lisboa, Portugal., Teixeira APS; Departamento de Ciências Médicas e da Saúde, Escola de Saúde e Desenvolvimento Humano & LAQV- REQUIMTE, IIFA, Universidade de Évora, R. Romão Ramalho, 59, 7000-671 Évora, Portugal., Rangel CM; Laboratório Nacional de Energia e Geologia, I.P., Estrada do Paço do Lumiar, 22, 1649-038 Lisboa, Portugal. |
| Jazyk: |
angličtina |
| Zdroj: |
Beilstein journal of organic chemistry [Beilstein J Org Chem] 2024 Jul 17; Vol. 20, pp. 1623-1634. Date of Electronic Publication: 2024 Jul 17 (Print Publication: 2024). |
| DOI: |
10.3762/bjoc.20.145 |
| Abstrakt: |
A new paradigm for energy is underway demanding decarbonized energy systems. Some of them rely on emerging electrochemical devices, crucial in hydrogen technologies, including fuel cells, CO 2 and water electrolysers, whose applications and performances depend on key components such as their separators/ion-exchange membranes. The most studied and already commercialized Nafion membrane shows great chemical stability, but its water content limits its high proton conduction to a limited range of operating temperatures. Here, we report the synthesis of a new series of triazinephosphonate derivatives and their use as dopants in the preparation of new modified Nafion membranes. The triazinephosphonate derivatives were prepared by substitution of chlorine atoms in cyanuric chloride. Diverse conditions were used to obtain the trisubstituted (4-hydroxyphenyl)triazinephosphonate derivatives and the (4-aminophenyl)triazinephosphonate derivatives, but with these amino counterparts, only the disubstituted compounds were obtained. The new modified Nafion membranes were prepared by casting incorporation of the synthesized 1,3,5-triazinephosphonate (TPs) derivatives. The evaluation of the proton conduction properties of the new membranes and relative humidity (RH) conditions and at 60 °C, showed that they present higher proton conductivities than the prepared Nafion membrane and similar or better proton conductivities than commercial Nafion N115, in the same experimental conditions. The Nafion-doped membrane with compound TP2 with a 1.0 wt % loading showed the highest proton conductivity with 84 mS·cm -1 .
(Copyright © 2024, Teixeira et al.) |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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