| Autor: |
Yewale MA; School of Mechanical Engineering, Yeungnam University, Gyeongsan 38541, Republic of Korea., Morankar PJ; School of Chemical Engineering, Yeungnam University, 280 Daehak-ro, Gyeongsan 38541, Republic of Korea., Kumar V; School of Mechanical Engineering, Yeungnam University, Gyeongsan 38541, Republic of Korea., Teli AM; Division of Electronics and Electrical Engineering, Dongguk University-Seoul, 30 Pildong-ro, Jung-gu, Seoul 04620, Republic of Korea., Beknalkar SA; Division of Electronics and Electrical Engineering, Dongguk University-Seoul, 30 Pildong-ro, Jung-gu, Seoul 04620, Republic of Korea., Dhas SD; Department of Electronic Engineering, Institute for Wearable Convergence Electronics, Kyung Hee University, 1732 Deogyeong-daero, Giheung-gu, Yongin 17104, Republic of Korea., Shin DK; School of Mechanical Engineering, Yeungnam University, Gyeongsan 38541, Republic of Korea. |
| Abstrakt: |
In this work, Ni 3 V 2 O 8 (NVO) and Ni 3 V 2 O 8 -reduced graphene oxide (NVO-rGO) are synthesized hydrothermally, and their extensive structural, morphological, and electrochemical characterizations follow subsequently. The synthetic materials' crystalline structure was confirmed by X-ray diffraction (XRD), and its unique marigold-like morphology was observed by field emission scanning electron microscopy (FESEM). The chemical states of the elements were investigated via X-ray photoelectron spectroscopy (XPS). Electrochemical impedance spectroscopy (EIS), Galvanostatic charge-discharge (GCD), and cyclic voltammetry (CV) were used to assess the electrochemical performance. A specific capacitance of 132 F/g, an energy density of 5.04 Wh/kg, and a power density of 187 W/kg were demonstrated by Ni 3 V 2 O 8 -rGO. Key electrochemical characteristics were b = 0.67; a transfer coefficient of 0.52; a standard rate constant of 6.07 × 10 -5 cm/S; a diffusion coefficient of 5.27 × 10 -8 cm 2 /S; and a series resistance of 1.65 Ω. By employing Ni 3 V 2 O 8 -rGO and activated carbon, an asymmetric supercapacitor with a specific capacitance of 7.85 F/g, an energy density of 3.52 Wh/kg, and a power density of 225 W/kg was achieved. The series resistance increased from 4.27 Ω to 6.63 Ω during cyclic stability tests, which showed 99% columbic efficiency and 87% energy retention. The potential of Ni 3 V 2 O 8 -rGO as a high-performance electrode material for supercapacitors is highlighted by these findings. |
