A H 2 @C 60 1 H NMR probe for sensitively detecting the supramolecular interactions between a molecular tweezer and C 60 .

Autor: He Y; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China. xhisaac@csu.edu.cn., Yu Z; Institute of Optical Materials and Chemical Biology, Guangxi Key Laboratory of Electrochemical Energy Materials, School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004, P. R. China., Jiang Y; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China. xhisaac@csu.edu.cn., Zhu J; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China. xhisaac@csu.edu.cn., Yao SX; Mechanical Engineering Department, University of Vermont, Burlington, Vermont, 05401, USA., Liang W; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China. xhisaac@csu.edu.cn., Diederich F; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China. xhisaac@csu.edu.cn., Saunders M; Department of Chemistry, Yale University, 225 Prospect Street, New Haven CT06511, USA., Xu H; College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China. xhisaac@csu.edu.cn.
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2024 Aug 13; Vol. 60 (66), pp. 8716-8719. Date of Electronic Publication: 2024 Aug 13.
DOI: 10.1039/d4cc02695k
Abstrakt: Herein, we firstly utilized H 2 @C 60 to monitor the supramolecular interaction between a pH-driven resorcin[4]arene molecular tweezer and C 60 with a notable 1 H NMR chemical shift change ( ca. 0.34 ppm). This work provides a new strategy for detecting weak or complex supramolecular interactions.
Databáze: MEDLINE