Boron-Nitrogen-Containing Benzene Valence Isomers.

Autor: Ozaki T; Department of Chemistry, Boston College, Chestnut Hill, Massachusetts, 02467-3860, USA., Liu SY; Department of Chemistry, Boston College, Chestnut Hill, Massachusetts, 02467-3860, USA.
Jazyk: angličtina
Zdroj: Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2024 Oct 01; Vol. 30 (55), pp. e202402544. Date of Electronic Publication: 2024 Sep 17.
DOI: 10.1002/chem.202402544
Abstrakt: Benzene is one of the most ubiquitous structural motifs in chemistry. The valence isomers of benzene have also attracted synthetic chemists' attention due to their unique structures, bonding, and reactivity. We have been investigating boron-nitrogen-containing benzene valence isomers via photoisomerization of 1,2-azaborines. In this contribution, we summarize recent developments of these highly strained BN-heterocyclic compounds including their synthesis, characterization, proposed mechanism of formation, and their potential applications.
(© 2024 The Author(s). Chemistry - A European Journal published by Wiley-VCH GmbH.)
Databáze: MEDLINE
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