Ionic Liquids with Benzenesulfonate Anions: Non-Fluorinated, Thermally Stable Anion Options.

Autor:	Soltani M; Department of Chemistry, University of South Alabama, Mobile, Alabama 36688, United States., Siu B; Department of Chemical & Biomolecular Engineering, University of South Alabama, Mobile, Alabama 36688, United States., Vo M; Department of Chemistry, University of South Alabama, Mobile, Alabama 36688, United States., West KN; Department of Chemical & Biomolecular Engineering, University of South Alabama, Mobile, Alabama 36688, United States., Adu C; Department of Chemistry, State University of New York at Oswego, Oswego, New York 13126, United States., Mirjafari A; Department of Chemistry, State University of New York at Oswego, Oswego, New York 13126, United States., Davis JH Jr; Department of Chemistry, University of South Alabama, Mobile, Alabama 36688, United States.
Jazyk:	angličtina
Zdroj:	ACS applied engineering materials [ACS Appl Eng Mater] 2023 Jan 27; Vol. 1 (1), pp. 690-695. Date of Electronic Publication: 2023 Jan 13.
DOI:	10.1021/acsaenm.2c00229
Abstrakt:	Thermally resistant materials have been sought after for use as lubricants, heat transfer fluids, high temperature structural materials, and other applications where thermal stability is required or desired. Herein, we present a new class of thermally robust ionic liquids containing inexpensive benezenesulfonate anions with profound long-term, high-temperature aerobic stability - i.e., no mass loss in 96 hours at 300 °C in air. A coherent correlation between melting and glass transition temperatures and the location and type of the anions was observed. Our work indicates that these systems can be designed to form thermally stable, low-melting organic salts, providing valuable design insights for engineering of their structure-property-function relationships. Competing Interests: The authors declare no competing financial interest.
Databáze:	MEDLINE
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