What's Next for First Row Fluorometallacycles?

Autor: Baker RT; Department of Chemistry and Biomolecular Sciences and CCRI, University of Ottawa, 10 Marie Curie, Ottawa, ON K1N 6N5, Canada., Mangin LP
Jazyk: angličtina
Zdroj: Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2024 Oct 07; Vol. 63 (41), pp. e202410307. Date of Electronic Publication: 2024 Sep 05.
DOI: 10.1002/anie.202410307
Abstrakt: Hydrocarbon-derived metallacycles have been identified as key intermediates in a host of catalyzed transformations of unsaturated organic substrates. In contrast, our knowledge of analogous reactivity of fluorometallacycles is underdeveloped and largely confined to first row metals. Our summary of recent advances aims to inform young investigators of the exciting challenges offered by this pursuit.
(© 2024 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.)
Databáze: MEDLINE