Copper-oxygen adducts: new trends in characterization and properties towards C-H activation.

Autor: De Tovar J; Université Grenoble-Alpes, CNRS, Département de Chimie Moléculaire Grenoble France catherine.belle@univ-grenoble-alpes.fr., Leblay R; Aix Marseille Univ, CNRS, Centrale Marseille, iSm2, Institut des Sciences Moléculaires de Marseille Marseille France marius.reglier@univ-amu.fr jalila.simaan@univ-amu.fr., Wang Y; Aix Marseille Univ, CNRS, Centrale Marseille, iSm2, Institut des Sciences Moléculaires de Marseille Marseille France marius.reglier@univ-amu.fr jalila.simaan@univ-amu.fr., Wojcik L; Université de Brest, Laboratoire de Chimie, Electrochimie Moléculaires et Chimie Analytique Brest France lepoul@univ-brest.fr., Thibon-Pourret A; Université Grenoble-Alpes, CNRS, Département de Chimie Moléculaire Grenoble France catherine.belle@univ-grenoble-alpes.fr., Réglier M; Aix Marseille Univ, CNRS, Centrale Marseille, iSm2, Institut des Sciences Moléculaires de Marseille Marseille France marius.reglier@univ-amu.fr jalila.simaan@univ-amu.fr., Simaan AJ; Aix Marseille Univ, CNRS, Centrale Marseille, iSm2, Institut des Sciences Moléculaires de Marseille Marseille France marius.reglier@univ-amu.fr jalila.simaan@univ-amu.fr., Le Poul N; Université de Brest, Laboratoire de Chimie, Electrochimie Moléculaires et Chimie Analytique Brest France lepoul@univ-brest.fr., Belle C; Université Grenoble-Alpes, CNRS, Département de Chimie Moléculaire Grenoble France catherine.belle@univ-grenoble-alpes.fr.
Jazyk: angličtina
Zdroj: Chemical science [Chem Sci] 2024 May 13; Vol. 15 (27), pp. 10308-10349. Date of Electronic Publication: 2024 May 13 (Print Publication: 2024).
DOI: 10.1039/d4sc01762e
Abstrakt: This review summarizes the latest discoveries in the field of C-H activation by copper monoxygenases and more particularly by their bioinspired systems. This work first describes the recent background on copper-containing enzymes along with additional interpretations about the nature of the active copper-oxygen intermediates. It then focuses on relevant examples of bioinorganic synthetic copper-oxygen intermediates according to their nuclearity (mono to polynuclear). This includes a detailed description of the spectroscopic features of these adducts as well as their reactivity towards the oxidation of recalcitrant C sp 3 -H bonds. The last part is devoted to the significant expansion of heterogeneous catalytic systems based on copper-oxygen cores ( i.e. within zeolite frameworks).
Competing Interests: There are no conflicts to declare.
(This journal is © The Royal Society of Chemistry.)
Databáze: MEDLINE
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