| Autor: |
Dhaene E; Department of Chemistry, University of Basel, Mattenstrasse 22, 4058 Basel, Switzerland. Jonathan.DeRoo@unibas.ch., Seno C; Department of Chemistry, University of Basel, Mattenstrasse 22, 4058 Basel, Switzerland. Jonathan.DeRoo@unibas.ch., De Roo J; Department of Chemistry, University of Basel, Mattenstrasse 22, 4058 Basel, Switzerland. Jonathan.DeRoo@unibas.ch. |
| Jazyk: |
angličtina |
| Zdroj: |
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2024 Jul 16; Vol. 53 (28), pp. 11769-11777. Date of Electronic Publication: 2024 Jul 16. |
| DOI: |
10.1039/d4dt01280a |
| Abstrakt: |
We revisited the synthesis of zirconium(IV) and hafnium(IV) alkoxides, namely the metal isopropoxide isopropanol complex (M(OiPr) 4 ·iPrOH, M = Zr, Hf) and the metal sec - and tert -butoxide (M(O s Bu) 4 and M(O t Bu) 4 , M = Zr, Hf). We optimized the most convenient synthesis methods and compared the products with commercial sources. En route to the metal sec - and tert -butoxides, we synthesized the metal diethylamido complex (M(NEt 2 ) 4 , M = Zr, Hf). |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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