| Autor: |
Bera P; Department of Chemistry, Indian Institute of Technology Guwahati, 781039 Guwahati, Assam, India., Mukherjee S; Department of Chemistry, Indian Institute of Technology Guwahati, 781039 Guwahati, Assam, India., Venturi DM; Institute of Inorganic Chemistry, Christian-Albrechts-University Kiel, 24118 Kiel, Germany., Ruser N; Institute of Inorganic Chemistry, Christian-Albrechts-University Kiel, 24118 Kiel, Germany., Biswas S; Department of Chemistry, Indian Institute of Technology Guwahati, 781039 Guwahati, Assam, India. |
| Abstrakt: |
An alarming increase in the use of pesticides and organoarsenic compounds and their toxic impacts on the environment have inspired us to develop a selective and highly sensitive sensor for the detection of these pollutants. Herein, a bio-friendly, low-cost Al-based luminescent metal-organic framework ( 1' )-based fluorescent material is demonstrated that helps in sustaining water quality by rapid monitoring and quantification of a long-established pesticide (pendimethalin) and a widely employed organoarsenic feed additive (roxarsone). A pyridine-functionalized porous aluminum-based metal-organic framework (Al-MOF) was solvothermally synthesized. After activation, it was used for fast (<10 s) and selective turn-off detection of roxarsone and pendimethalin over other competitive analytes. This is the first MOF-based recyclable sensor for pendimethalin with a remarkably low limit of detection (LOD, 14.4 nM). Real-time effectiveness in detection of pendimethalin in various vegetable and food extracts was successfully verified. Moreover, the aqueous-phase recyclable detection of roxarsone with an ultralow detection limit (13.1 nM) makes it a potential candidate for real-time application. The detection limits for roxarsone and pendimethalin are lower than the existing luminescent material based sensors. Furthermore, the detection of roxarsone in different environmental water and a wide pH range with a good recovery percentage was demonstrated. In addition, a cheap and bio-friendly 1'@chitosan@paper strip composite was prepared and successfully employed for the hands-on detection of pendimethalin and roxarsone. The turn-off behavior of 1' in the presence of pendimethalin and roxarsone was examined systematically, and plausible mechanistic pathways were proposed with the help of multiple experimental evidences. |
