Length dependent reversible off-on activation of photo-switchable relay anion transporters.
| Autor: | Johnson TG; Chemistry Research Laboratory, Mansfield Road, Oxford, OX1 3TA, UK. matthew.langton@chem.ox.ac.uk., Sadeghi-Kelishadi A; Chemistry Research Laboratory, Mansfield Road, Oxford, OX1 3TA, UK. matthew.langton@chem.ox.ac.uk., Langton MJ; Chemistry Research Laboratory, Mansfield Road, Oxford, OX1 3TA, UK. matthew.langton@chem.ox.ac.uk. |
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| Jazyk: | angličtina |
| Zdroj: | Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2024 Jul 09; Vol. 60 (56), pp. 7160-7163. Date of Electronic Publication: 2024 Jul 09. |
| DOI: | 10.1039/d4cc02603a |
| Abstrakt: | A homologous series of azobenzene-derived photo-switchable ion relay transporters is reported. We reveal that both the length and geometry of the relay strongly affect transport rate, allowing the relative activity of the E and Z isomers to be reversed and hence the wavelengths of light used for on and off switching to be exchanged. |
| Databáze: | MEDLINE |
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