| Autor: |
Kim HS; Materials Science, California Institute of Technology, Pasadena, CA 91125, USA.; Department of Materials Science and Engineering, Northwestern University, Evanston, IL 60208, USA.; Department of Materials Science and Engineering, University of Seoul, Seoul, 02504, Republic of Korea. hyunsik.kim@uos.ac.kr., Heinz NA; Materials Science, California Institute of Technology, Pasadena, CA 91125, USA., Gibbs ZM; Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125, USA., Kim J; Department of Materials Science and Engineering, University of Seoul, Seoul, 02504, Republic of Korea. hyunsik.kim@uos.ac.kr., Snyder GJ; Materials Science, California Institute of Technology, Pasadena, CA 91125, USA.; Department of Materials Science and Engineering, Northwestern University, Evanston, IL 60208, USA. |
| Abstrakt: |
Nanostructured thermoelectric materials ideally reduce lattice thermal conductivity without harming the electrical properties. Thus, to truly improve the thermoelectric performance, the quality factor, which is proportional to the weighted mobility divided by the lattice thermal conductivity of the material, must be improved. Precipitates of In 2 Te 3 form in the state-of-the-art Bi 2 Te 3 with crystallographic alignment to the Bi 2 Te 3 structure. Like epitaxy in films, this can be called endotaxy in solids. This natural epitaxy in a 3-dimensional solid is ideally situated to scatter phonons but produces minimal electronic scattering and, therefore, maintains high mobility. Here, we study the effects of In-alloying in Bi 2 Te 3 at high In concentrations (about 4 at%), enough to produce the endotaxial microstructure. It is found that such concentrations of indium in Bi 2 Te 3 significantly alter the electronic structure, reducing the effective mass and weighted mobility so significantly as to effectively destroy the thermoelectric properties even though the lattice thermal conductivity is successfully reduced. |
