Mechanochemical Synthesis of MOF-303 and Its CO 2 Adsorption at Ambient Conditions.

Autor: Głowniak S; Institute of Chemistry, Military University of Technology, 00-908 Warsaw, Poland., Szczęśniak B; Institute of Chemistry, Military University of Technology, 00-908 Warsaw, Poland., Choma J; Institute of Chemistry, Military University of Technology, 00-908 Warsaw, Poland., Jaroniec M; Department of Chemistry and Biochemistry & Advanced Materials and Liquid Crystal Institute, Kent State University, Kent, OH 44242, USA.
Jazyk: angličtina
Zdroj: Molecules (Basel, Switzerland) [Molecules] 2024 Jun 06; Vol. 29 (11). Date of Electronic Publication: 2024 Jun 06.
DOI: 10.3390/molecules29112698
Abstrakt: Metal-organic structures have great potential for practical applications in many areas. However, their widespread use is often hindered by time-consuming and expensive synthesis procedures that often involve hazardous solvents and, therefore, generate wastes that need to be remediated and/or recycled. The development of cleaner, safer, and more sustainable synthesis methods is extremely important and is needed in the context of green chemistry. In this work, a facile mechanochemical method involving water-assisted ball milling was used for the synthesis of MOF-303. The obtained MOF-303 exhibited a high specific surface area of 1180 m 2 /g and showed an excellent CO 2 adsorption capacity of 9.5 mmol/g at 0 °C and under 1 bar.
Databáze: MEDLINE
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