Thermoluminescence properties and new insights on the UV-vis absorption features of colorless quartz after γ-ray irradiation.

Autor: Ngoc T; Institute of Research and Development, Duy Tan University Da Nang 550000 Vietnam.; Faculty of Natural Sciences, Duy Tan University Da Nang 550000 Vietnam., Ca NX; Institute of Science and Technology, TNU-University of Sciences Thai Nguyen Viet Nam., Thanh NT; Institute of Materials Science, Vietnam Academy of Science and Technology Hanoi Vietnam., Hung NM; Thuyloi University 175 Tay Son, Dong Da Hanoi Vietnam phanvando@tlu.edu.vn., Du PT; Thuyloi University 175 Tay Son, Dong Da Hanoi Vietnam phanvando@tlu.edu.vn., Chung Thuy TT; Thuyloi University 175 Tay Son, Dong Da Hanoi Vietnam phanvando@tlu.edu.vn., Huong NT; Thuyloi University 175 Tay Son, Dong Da Hanoi Vietnam phanvando@tlu.edu.vn., Van Do P; Thuyloi University 175 Tay Son, Dong Da Hanoi Vietnam phanvando@tlu.edu.vn.
Jazyk: angličtina
Zdroj: RSC advances [RSC Adv] 2024 Jun 17; Vol. 14 (27), pp. 19154-19166. Date of Electronic Publication: 2024 Jun 17 (Print Publication: 2024).
DOI: 10.1039/d4ra03116d
Abstrakt: In this paper, we present the results of research on the thermoluminescence (TL) and optical absorption (OA) properties of colorless natural quartz (including natural quartz samples, sodium ion (Na + ) rich samples (by diffusion), and alkali metal (M + ) ion poor samples (by sweep)). In detail, the relationship between the TL glow peaks and the emission wavelength was determined. The dynamics parameters ( E T , s , τ ) have been computed for all TL peaks on the glow curve. The recombination mechanism electron-hole with the participation of the region energy has been determined for all electron traps in the temperature range of 50-430 °C through thermally stimulated conductivity measurement (TSC). Nonlinearity and approaching signal saturation are observed at doses above 22 Gy for the electron trap at 110 °C, above 45 Gy for the electron trap at 238 °C, and 80 Gy for the electron traps at 325 °C and 375 °C. The role of irradiation and heat treatment in the formation of absorption centers as well as the relationship of these centers to electronic traps have been also investigated in detail. The role of M + ions and hydrogen ions (H + ) for the absorption bands in the UV-vis region has been discussed. The results of the combination of the TL measurement and monochromatic light absorption according to temperature show that the TL process occurs concurrently with the reduction of the absorbent center produced in the irradiation process.
Competing Interests: There are no conflicts to declare.
(This journal is © The Royal Society of Chemistry.)
Databáze: MEDLINE
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