Adsorption of terbutaline β-agonists from wastewater by mechano-synthesized iron oxide nanoparticles modified copper (II) isonicotinate metal-organic framework.

Autor: Usman A; Analytical Chemistry Unit, Faculty of Science and Marine Environment, Universiti Malaysia Terengganu, 21030, Kuala Nerus, Terengganu, Malaysia; Department of Chemistry, College of Natural and Applied Science, Al-Qalam University Katsina, Katsina City, 2137, Katsina, Nigeria., Khoo KS; Department of Chemical Engineering and Materials Science, Yuan Ze University, Taoyuan, Taiwan; Centre for Herbal Pharmacology and Environmental Sustainability, Chettinad Hospital and Research Institute, Chettinad Academy of Research and Education, Kelambakkam, 603103, Tamil Nadu, India., Ariffin MM; Analytical Chemistry Unit, Faculty of Science and Marine Environment, Universiti Malaysia Terengganu, 21030, Kuala Nerus, Terengganu, Malaysia., Loh SH; Analytical Chemistry Unit, Faculty of Science and Marine Environment, Universiti Malaysia Terengganu, 21030, Kuala Nerus, Terengganu, Malaysia., Wan Mohd Khalik WMA; Analytical Chemistry Unit, Faculty of Science and Marine Environment, Universiti Malaysia Terengganu, 21030, Kuala Nerus, Terengganu, Malaysia., Yusoff HM; Analytical Chemistry Unit, Faculty of Science and Marine Environment, Universiti Malaysia Terengganu, 21030, Kuala Nerus, Terengganu, Malaysia., Zango ZU; Department of Chemistry, College of Natural and Applied Science, Al-Qalam University Katsina, Katsina City, 2137, Katsina, Nigeria. Electronic address: zakariyyazango@auk.edu.ng., Aldaghri O; Department of Physics, College of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU), Riyadh, 13318, Riyadh, Saudi Arabia., Ibnaouf KH; Department of Physics, College of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU), Riyadh, 13318, Riyadh, Saudi Arabia. Electronic address: khiahmed@imamu.edu.sa., Eisa MH; Department of Physics, College of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU), Riyadh, 13318, Riyadh, Saudi Arabia., Binzowaimil AM; Department of Physics, College of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU), Riyadh, 13318, Riyadh, Saudi Arabia., Lim JW; HICoE-Centre for Biofuel and Biochemical Research, Institute of Sustainable Energy, Department of Fundamental and Applied Sciences, Universiti Teknologi PETRONAS, 32610, Seri Iskandar, Perak Darul Ridzuan, Malaysia; Department of Biotechnology, Saveetha School of Engineering, Saveetha Institute of Medical and Technical Sciences, Saveetha University, Chennai, India.
Jazyk: angličtina
Zdroj: Environmental research [Environ Res] 2024 Oct 01; Vol. 258, pp. 119413. Date of Electronic Publication: 2024 Jun 12.
DOI: 10.1016/j.envres.2024.119413
Abstrakt: Frequent detection of terbutaline in wastewater highlights its potential risks to human health associated in the environment. Exposure to terbutaline through contaminated water sources or food chain have adverse effects to human health. This work emphasized on the removal of terbutaline from wastewater using adsorption technology. Mechanochemically synthesized [Cu(INA) 2 ] metal-organic frameworks (MOFs) and its magnetic composite ([Cu(INA) 2 ]-MOF@Fe 3 O 4 ) are designed with higher specific surface areas and tailored features to accommodate the molecular size and structure of terbutaline. Thus, batch experiment has been conducted using the [Cu(INA) 2 ]-MOF and [Cu(INA) 2 ]-MOF@Fe 3 O 4 for the terbutaline adsorption. The adsorption efficiency achieved by the MOFs was 91.8% and 99.3% for the Cu(INA) 2 ]-MOF and [Cu(INA) 2 ]-MOF@Fe 3 O 4 respectively. The optimum for the adsorption study included terbutaline concentration of 40 mg/L, adsorbent dose of 5 mg/L, pH of 11, temperature of 25 °C and equilibrium time of 40 min. The kinetics and isotherms have been described by pseudo-second order and Langmuir models, while the thermodynamics revealed the exothermic and spontaneous nature of the process. The promising performance of the MOFs is manifested on the ease of regeneration and reusability, achieving adsorption efficiency of 85.0% and 94.7% by the Cu(INA) 2 ]-MOF and [Cu(INA) 2 ]-MOF@Fe 3 O 4 , respectively at five consecutive cycles. The higher performance of the MOFs demonstrates their excellent potentialities for the terbutaline adsorption from the aqueous solution.
Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
(Copyright © 2024 Elsevier Inc. All rights reserved.)
Databáze: MEDLINE
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