Photoinduced decarboxylative germylation of α-fluoroacrylic acids: access to germylated monofluoroalkenes.

Autor: Lu XY; School of Materials and Chemical Engineering, ChuZhou University, Chu Zhou, 239000, China. xiaoyulu@mail.ustc.edu.cn., Qian YJ; School of Materials and Chemical Engineering, ChuZhou University, Chu Zhou, 239000, China. xiaoyulu@mail.ustc.edu.cn., Sun HL; School of Materials and Chemical Engineering, ChuZhou University, Chu Zhou, 239000, China. xiaoyulu@mail.ustc.edu.cn., Su MX; School of Materials and Chemical Engineering, ChuZhou University, Chu Zhou, 239000, China. xiaoyulu@mail.ustc.edu.cn., Wang ZZ; School of Materials and Chemical Engineering, ChuZhou University, Chu Zhou, 239000, China. xiaoyulu@mail.ustc.edu.cn., Jiang F; School of Materials and Chemical Engineering, ChuZhou University, Chu Zhou, 239000, China. xiaoyulu@mail.ustc.edu.cn., Zhou XY; School of Materials and Chemical Engineering, ChuZhou University, Chu Zhou, 239000, China. xiaoyulu@mail.ustc.edu.cn., Sun YX; School of Materials and Chemical Engineering, ChuZhou University, Chu Zhou, 239000, China. xiaoyulu@mail.ustc.edu.cn., Shi WL; School of Materials and Chemical Engineering, ChuZhou University, Chu Zhou, 239000, China. xiaoyulu@mail.ustc.edu.cn., Wan JR; School of Materials and Chemical Engineering, ChuZhou University, Chu Zhou, 239000, China. xiaoyulu@mail.ustc.edu.cn.
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2024 Jun 20; Vol. 60 (51), pp. 6556-6559. Date of Electronic Publication: 2024 Jun 20.
DOI: 10.1039/d4cc02037e
Abstrakt: Herein, a novel strategy is presented for the photoinduced decarboxylative and dehydrogenative cross-coupling of a wide range of α-fluoroacrylic acids with hydrogermanes. This methodology provides an efficient and robust approach for producing various germylated monofluoroalkenes with excellent stereoselectivity within a brief photoirradiation period. The feasibility of this reaction has been demonstrated through gram-scale reaction, conversion of germylated monofluoroalkenes, and modification of complex organic molecules.
Databáze: MEDLINE
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