The complexometric behavior of selected aroyl-S,N-ketene acetals shows that they are more than AIEgens.

Autor: Biesen L; Heinrich-Heine-Universität Düsseldorf, Math.-Nat. Fakultät, Institut für Organische Chemie und Makromolekulare Chemie, Universitätsstraße 1, 40225, Düsseldorf, Germany.; School of Chemistry, Joseph Black Building, University of Glasgow, Glasgow, G12 8QQ, UK., Müller TJJ; Heinrich-Heine-Universität Düsseldorf, Math.-Nat. Fakultät, Institut für Organische Chemie und Makromolekulare Chemie, Universitätsstraße 1, 40225, Düsseldorf, Germany. ThomasJJ.Mueller@hhu.de.
Jazyk: angličtina
Zdroj: Scientific reports [Sci Rep] 2024 May 31; Vol. 14 (1), pp. 12565. Date of Electronic Publication: 2024 May 31.
DOI: 10.1038/s41598-024-62100-4
Abstrakt: Using the established synthetic methods, aroyl-S,N-ketene acetals and subsequent bi- and multichromophores can be readily synthesized. Aside from pronounced AIE (aggregation induced emission) properties, these selected examples possess distinct complexometric behavior for various metals purely based on the underlying structural motifs. This affects the fluorescence properties of the materials which can be readily exploited for metal ion detection and for the formation of different metal-aroyl-S,N-ketene acetal complexes that were confirmed by Job plot analysis. In particular, gold(I), iron(III), and ruthenium (III) ions reveal complexation enhanced or quenched emission. For most dyes, weakly coodinating complexes were observed, only in case of a phenanthroline aroyl-S,N-ketene acetal multichromophore, measurements indicate the formation of a strongly coordinating complex. For this multichromophore, the complexation results in a loss of fluorescence intensity whereas for dimethylamino-aroyl-S,N-ketene acetals and bipyridine bichromophores, the observed quantum yield is nearly tripled upon complexation. Even if no stable complexes are formed, changes in absorption and emission properties allow for a simple ion detection.
(© 2024. The Author(s).)
Databáze: MEDLINE
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