Iron-catalyzed decarboxylative radical addition to chiral azomethine imines upon visible light.

Autor:	Fall A; INSA Rouen Normandie, Univ Rouen Normandie, CNRS, Normandie Univ, COBRA UMR 6014, INC3M FR 3038, F-76000 Rouen, France. jean-francois.briere@insa-rouen.fr., Magdei M; INSA Rouen Normandie, Univ Rouen Normandie, CNRS, Normandie Univ, COBRA UMR 6014, INC3M FR 3038, F-76000 Rouen, France. jean-francois.briere@insa-rouen.fr., Savchuk M; INSA Rouen Normandie, Univ Rouen Normandie, CNRS, Normandie Univ, COBRA UMR 6014, INC3M FR 3038, F-76000 Rouen, France. jean-francois.briere@insa-rouen.fr., Oudeyer S; INSA Rouen Normandie, Univ Rouen Normandie, CNRS, Normandie Univ, COBRA UMR 6014, INC3M FR 3038, F-76000 Rouen, France. jean-francois.briere@insa-rouen.fr., Beucher H; INSA Rouen Normandie, Univ Rouen Normandie, CNRS, Normandie Univ, COBRA UMR 6014, INC3M FR 3038, F-76000 Rouen, France. jean-francois.briere@insa-rouen.fr., Brière JF; INSA Rouen Normandie, Univ Rouen Normandie, CNRS, Normandie Univ, COBRA UMR 6014, INC3M FR 3038, F-76000 Rouen, France. jean-francois.briere@insa-rouen.fr.
Jazyk:	angličtina
Zdroj:	Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2024 Jun 13; Vol. 60 (49), pp. 6316-6319. Date of Electronic Publication: 2024 Jun 13.
DOI:	10.1039/d4cc01766h
Abstrakt:	Herein, we disclose an eco-efficient redox-neutral iron-catalyzed decarboxylative radical addition to chiral azomethine imines upon visible light (427 nm) giving cyclic hydrazine derivatives with dr ranging from 82 : 18 to >96 : 4. This earth-abundant metal promoted sequence proceeds efficiently under ligand-free conditions based on a LMCT process and opens a route to new chiral heterocycles.
Databáze:	MEDLINE
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