| Autor: |
Lang J; Department of Chemistry, University of Missouri, Columbia, MO 65211, USA. suitsa@missouri.edu., Foley CD; Department of Chemistry, University of Missouri, Columbia, MO 65211, USA. suitsa@missouri.edu., Thawoos S; Department of Chemistry, University of Missouri, Columbia, MO 65211, USA. suitsa@missouri.edu., Behzadfar A; Department of Chemistry, University of Missouri, Columbia, MO 65211, USA. suitsa@missouri.edu., Liu Y; Department of Chemistry, University of Missouri, Columbia, MO 65211, USA. suitsa@missouri.edu., Zádor J; Combustion Research Facility, Sandia National Laboratories, Livermore, California 94551, USA. jzador@sandia.gov., Suits AG; Department of Chemistry, University of Missouri, Columbia, MO 65211, USA. suitsa@missouri.edu. |
| Abstrakt: |
Sulfur atoms serve as key players in diverse chemical processes, from astrochemistry at very low temperature to combustion at high temperature. Building upon our prior findings, showing cyclization to thiophenes following the reaction of ground-state sulfur atoms with dienes, we here extend this investigation to include many additional reaction products, guided by detailed theoretical predictions. The outcomes highlight the complex formation of products during intersystem crossing (ISC) to the singlet surfaces. Here, we employed crossed-beam velocity map imaging and high-level ab initio methods to explore the reaction of S( 3 P) with 1,3-butadiene and isoprene under single-collision conditions and in low-temperature flows. For the butadiene reaction, our experimental results show the formation of thiophene via H 2 loss, a 2 H -thiophenyl radical through H loss, and thioketene through ethene loss at a slightly higher collision energy compared to previous observations. Complementary Chirped-Pulse Fourier-Transform mmWave spectroscopy (CP-FTmmW) measurements in a uniform flow confirmed the formation of thioketene in the reaction at 20 K. For the isoprene reaction, we observed analogous products along with the 2 H -thiophenyl radical arising from methyl loss and C 3 H 4 S (loss of ethene or H 2 + acetylene). CP-FTmmW detected the formation of thioformaldehyde via loss of 1,3-butadiene, again in the 20 K flow. Coupled-cluster calculations on the pathways found by the automated kinetic workflow code KinBot support these findings and indicate ISC to the singlet surface, leading to the generation of various long-lived intermediates, including 5-membered heterocycles. |
