| Autor: |
de Souza JPR; Institute of Chemistry, University of Brasília, Asa Norte, Brasilia 70910-900, Brazil., Garnier J; Institute of Geosciences, University of Brasília, Asa Norte, Brasilia 70910-900, Brazil., Quintarelli JM; Institute of Geosciences, University of Brasília, Asa Norte, Brasilia 70910-900, Brazil., de Sousa Tonhá M; Institute of Geosciences, University of Brasília, Asa Norte, Brasilia 70910-900, Brazil., Roig HL; Institute of Geosciences, University of Brasília, Asa Norte, Brasilia 70910-900, Brazil., Seyler P; HydroSciences Montpellier, Université de Montpellier, Institut de Recherche Our le Développement, Centre National de la Recherche Scientifique, 34090 Montpellier, France., de Souza JR; Institute of Chemistry, University of Brasília, Asa Norte, Brasilia 70910-900, Brazil. |
| Abstrakt: |
Artisanal small-scale gold mining (ASGM), an increasingly prevalent activity in South America, generates mercury-contaminated tailings that are often disposed of in the environment, leading to the introduction of mercury into ecosystems and the food web, where it bioaccumulates. Therefore, studying the geochemical processes involved in the desorption and dissolution of mercury in these tailings is essential for critical risk evaluations in the short and long term. For this purpose, sequential extraction procedures (SEPs) can be useful because they help to identify the phases to which Hg is associated, although they also have limitations such as a lack of selectivity and specificity. In this work, we propose a modified four-step SEP: exchangeable mercury (F1), oxidizable mercury (F2), mercury bound to Fe oxides (F3), and strongly bound mercury (F4). To test this adapted sequential extraction method, we evaluated the Hg contamination in mercury-contaminated tailings of the Amazon basin. The results revealed a total mercury concentration of 103 ± 16 mg·kg -1 in the tailings, with a significant portion in F1 (28% of the total), where Hg was bioavailable. The large Hg concentration in F3 (36%) suggested that Fe oxides likely contribute to mercury retention. Together, the SEP results emphasize the urgent need for improved surveillance of gold mining activities and responsible tailings management practices to mitigate environmental contamination and safeguard the health of the Amazon ecosystem. |
