Functional metal-organic liquids.
| Autor: | Ma N; International Center for Young Scientists (ICYS), National Institute for Materials Science 1-1 Namiki Tsukuba Ibaraki 305-0044 Japan ma.nattapol@nims.go.jp.; Centre for Membrane Separations, Adsorption, Catalysis and Spectroscopy (cMACS), KU Leuven Celestijnenlaan 200F 3001 Leuven Belgium., Kosasang S; Department of Chemistry, Graduate School of Science, Kyoto University Kitashirakawa-Oiwake-cho, Sakyo-ku Kyoto 606-8502 Japan horike.satoshi.3r@kyoto-u.ac.jp., Berdichevsky EK; Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University Katsura, Nishikyo-ku Kyoto 615-8510 Japan., Nishiguchi T; Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University Katsura, Nishikyo-ku Kyoto 615-8510 Japan., Horike S; Department of Chemistry, Graduate School of Science, Kyoto University Kitashirakawa-Oiwake-cho, Sakyo-ku Kyoto 606-8502 Japan horike.satoshi.3r@kyoto-u.ac.jp.; Institute for Integrated Cell-Material Sciences, Institute for Advanced Study, Kyoto University Yoshida-Honmachi, Sakyo-ku Kyoto 606-8501 Japan.; Department of Materials Science and Engineering, School of Molecular Science and Engineering, Vidyasirimedhi Institute of Science and Technology Rayong 21210 Thailand. |
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| Jazyk: | angličtina |
| Zdroj: | Chemical science [Chem Sci] 2024 May 08; Vol. 15 (20), pp. 7474-7501. Date of Electronic Publication: 2024 May 08 (Print Publication: 2024). |
| DOI: | 10.1039/d4sc01793e |
| Abstrakt: | For decades, the study of coordination polymers (CPs) and metal-organic frameworks (MOFs) has been limited primarily to their behavior as crystalline solids. In recent years, there has been increasing evidence that they can undergo reversible crystal-to-liquid transitions. However, their "liquid" states have primarily been considered intermediate states, and their diverse properties and applications of the liquid itself have been overlooked. As we learn from organic polymers, ceramics, and metals, understanding the structures and properties of liquid states is essential for exploring new properties and functions that are not achievable in their crystalline state. This review presents state-of-the-art research on the liquid states of CPs and MOFs while discussing the fundamental concepts involved in controlling them. We consider the different types of crystal-to-liquid transitions found in CPs and MOFs while extending the interpretation toward other functional metal-organic liquids, such as metal-containing ionic liquids and porous liquids, and try to suggest the unique features of CP/MOF liquids. We highlight their potential applications and present an outlook for future opportunities. Competing Interests: There are no conflicts to declare. (This journal is © The Royal Society of Chemistry.) |
| Databáze: | MEDLINE |
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