Surface Plasmon Resonance-Mediated Photocatalytic H 2 Generation.

Autor: Zhang X; Huangpu H2 Energy Innovation Center, School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou, 510006, P. R. China., Wang C; Bingtuan Energy Development Institute, Shihezi University, Shihezi City, Xinjiang Uygur Autonomous Region, 832000, P. R. China., Zhang M; School of Semiconductor Science and Technology, South China Normal University, Foshan, Guangdong 528225, P. R. China., Luo D; Huangpu H2 Energy Innovation Center, School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou, 510006, P. R. China., Ye S; Huangpu H2 Energy Innovation Center, School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou, 510006, P. R. China., Weng B; CAS Key Laboratory of Urban Pollutant Conversion, Institute of Urban Environment Chinese Academy of Sciences, 1799 Jimei Road, Xiamen, 361021, P. R. China.; University of Chinese Academy of Sciences, 19 A Yuquan Road, Beijing, 100049, P. R. China.
Jazyk: angličtina
Zdroj: ChemSusChem [ChemSusChem] 2024 Nov 11; Vol. 17 (21), pp. e202400513. Date of Electronic Publication: 2024 Jun 28.
DOI: 10.1002/cssc.202400513
Abstrakt: The limited yield of H 2 production has posed a significant challenge in contemporary research. To address this issue, researchers have turned to the application of surface plasmon resonance (SPR) materials in photocatalytic H 2 generation. SPR, arising from collective electron oscillations, enhances light absorption and facilitates efficient separation and transfer of electron-hole pairs in semiconductor systems, thereby boosting photocatalytic H 2 production efficiency. However, existing reviews predominantly focus on SPR noble metals, neglecting non-noble metals and SPR semiconductors. In this review, we begin by elucidating five different SPR mechanisms, covering hot electron injection, electric field enhancement, light scattering, plasmon-induced resonant energy transfer, and photo-thermionic effect, by which SPR enhances photocatalytic activity. Subsequently, a comprehensive overview follows, detailing the application of SPR materials-metals, non-noble metals, and SPR semiconductors-in photocatalytic H 2 production. Additionally, a personal perspective is offered on developing highly efficient SPR-based photocatalysis systems for solar-to-H 2 conversion in the future. This review aims to guide the development of next-gen SPR-based materials for advancing solar-to-fuel conversion.
(© 2024 Wiley-VCH GmbH.)
Databáze: MEDLINE
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