Surface-Enhanced Raman Spectroscopy: Current Understanding, Challenges, and Opportunities.

Autor: Ma H; State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (i-ChEM), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China., Pan SQ; State Key Laboratory of Marine Environmental Science, College of the Environment and Ecology, Fujian Provincial Key Laboratory for Coastal Ecology and Environmental Studies, Center for Marine Environmental Chemistry & Toxicology, Xiamen University, Xiamen 361102, China., Wang WL; State Key Laboratory of Marine Environmental Science, College of the Environment and Ecology, Fujian Provincial Key Laboratory for Coastal Ecology and Environmental Studies, Center for Marine Environmental Chemistry & Toxicology, Xiamen University, Xiamen 361102, China., Yue X; State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (i-ChEM), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China., Xi XH; State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (i-ChEM), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China., Yan S; State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (i-ChEM), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China., Wu DY; State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (i-ChEM), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China., Wang X; State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (i-ChEM), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China., Liu G; State Key Laboratory of Marine Environmental Science, College of the Environment and Ecology, Fujian Provincial Key Laboratory for Coastal Ecology and Environmental Studies, Center for Marine Environmental Chemistry & Toxicology, Xiamen University, Xiamen 361102, China., Ren B; State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials (i-ChEM), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
Jazyk: angličtina
Zdroj: ACS nano [ACS Nano] 2024 Jun 04; Vol. 18 (22), pp. 14000-14019. Date of Electronic Publication: 2024 May 19.
DOI: 10.1021/acsnano.4c02670
Abstrakt: While surface-enhanced Raman spectroscopy (SERS) has experienced substantial advancements since its discovery in the 1970s, it is an opportunity to celebrate achievements, consider ongoing endeavors, and anticipate the future trajectory of SERS. In this perspective, we encapsulate the latest breakthroughs in comprehending the electromagnetic enhancement mechanisms of SERS, and revisit CT mechanisms of semiconductors. We then summarize the strategies to improve sensitivity, selectivity, and reliability. After addressing experimental advancements, we comprehensively survey the progress on spectrum-structure correlation of SERS showcasing their important role in promoting SERS development. Finally, we anticipate forthcoming directions and opportunities, especially in deepening our insights into chemical or biological processes and establishing a clear spectrum-structure correlation.
Databáze: MEDLINE