| Autor: |
Daliran S; Department of Organic Chemistry, Faculty of Chemistry, Lorestan University, Khorramabad 68151-44316, Iran. daliran.s@lu.ac.ir., Oveisi AR; Department of Chemistry, University of Zabol, P.O. Box: 98615-538, Zabol, Iran. aroveisi@uoz.ac.ir., Kung CW; Department of Chemical Engineering, National Cheng Kung University, 1 University Road, Tainan City 70101, Taiwan. cwkung@mail.ncku.edu.tw., Sen U; Department of Materials Science and Engineering, Faculty of Engineering, Eskisehir Technical University, Eskisehir 26555, Turkey., Dhakshinamoorthy A; Departamento de Quimica, Universitat Politècnica de València, Av. De los Naranjos s/n, 46022 Valencia, Spain.; School of Chemistry, Madurai Kamaraj University, Madurai 625021, India., Chuang CH; Department of Chemical Engineering, National Cheng Kung University, 1 University Road, Tainan City 70101, Taiwan. cwkung@mail.ncku.edu.tw., Khajeh M; Department of Chemistry, University of Zabol, P.O. Box: 98615-538, Zabol, Iran. aroveisi@uoz.ac.ir., Erkartal M; Department of Basic Sciences, Faculty of Engineering, Architecture and Design, Bartin University, Bartin 74110, Turkey., Hupp JT; Department of Chemistry, Northwestern University, Evanston, Illinois 60208, USA. j-hupp@northwestern.edu. |
| Abstrakt: |
This comprehensive review explores the diverse applications of defective zirconium-based metal-organic frameworks (Zr-MOFs) in energy and environmental remediation. Zr-MOFs have gained significant attention due to their unique properties, and deliberate introduction of defects further enhances their functionality. The review encompasses several areas where defective Zr-MOFs exhibit promise, including environmental remediation, detoxification of chemical warfare agents, photocatalytic energy conversions, and electrochemical applications. Defects play a pivotal role by creating open sites within the framework, facilitating effective adsorption and remediation of pollutants. They also contribute to the catalytic activity of Zr-MOFs, enabling efficient energy conversion processes such as hydrogen production and CO 2 reduction. The review underscores the importance of defect manipulation, including control over their distribution and type, to optimize the performance of Zr-MOFs. Through tailored defect engineering and precise selection of functional groups, researchers can enhance the selectivity and efficiency of Zr-MOFs for specific applications. Additionally, pore size manipulation influences the adsorption capacity and transport properties of Zr-MOFs, further expanding their potential in environmental remediation and energy conversion. Defective Zr-MOFs exhibit remarkable stability and synthetic versatility, making them suitable for diverse environmental conditions and allowing for the introduction of missing linkers, cluster defects, or post-synthetic modifications to precisely tailor their properties. Overall, this review highlights the promising prospects of defective Zr-MOFs in addressing energy and environmental challenges, positioning them as versatile tools for sustainable solutions and paving the way for advancements in various sectors toward a cleaner and more sustainable future. |
