| Autor: |
Gharsallah S; Laboratory of Inorganic Chemistry, LR17-ES-07, Faculty of Science, University of Sfax, Sfax 3018, Tunisia., Khitouni N; Laboratory of Inorganic Chemistry, LR17-ES-07, Faculty of Science, University of Sfax, Sfax 3018, Tunisia., Mallah A; Department of Chemistry, College of Science, Qassim University, Buraydah 51452, Saudi Arabia., Alsawi A; Department of Physics, College of Science, Qassim University, Buraydah 51452, Saudi Arabia., Alluhayb AH; Department of Chemistry, College of Science, Qassim University, Buraydah 51452, Saudi Arabia., Khitouni M; Department of Chemistry, College of Science, Qassim University, Buraydah 51452, Saudi Arabia., Charnay C; Charles Gerhard Institut, UMR-5253 CNRS-UM-ENSCM, University of Montpellier, Place E, Bataillon, CEDEX 5, F-34095 Montpellier, France., Chemingui M; Laboratory of Inorganic Chemistry, LR17-ES-07, Faculty of Science, University of Sfax, Sfax 3018, Tunisia. |
| Abstrakt: |
A serious risk that harms the safe use of water and affects aquatic ecosystems is water pollution. This occurs when the water's natural equilibrium is disrupted by an excessive amount of substances, both naturally occurring and as a byproduct of human activities, that have varied degrees of toxicity. Radiation from Cs isotopes, which are common components of radioactive waste and are known for their long half-lives (30 years), which are longer than the natural decay processes, is a major source of contamination. Adsorption is a commonly used technique for reducing this kind of contamination, and zeolite chabazite has been chosen as the best adsorbent for cesium in this particular situation. The purpose of this research is to investigate a composite material based on magnesium phosphate cement (MPC). Magnesium oxide (MgO), potassium dihydrogen phosphate (KH 2 PO 4 ), and properly selected retarders are used to create the MPC. The optimal conditions for this composite material are investigated through the utilization of X-ray diffraction, scanning electron microscopy, BET surface area analysis, and atomic absorption spectroscopy. The principal aim is to enable innovations in the elimination of radioactive waste-contaminated water using effective cesium removal. The most promising results were obtained by using KH 2 PO 4 as an acid, and MgO as a base, and aiming for an M/P ratio of two or four. Furthermore, we chose zeolite chabazite as a crucial component. The best adsorption abilities for Cs were found at Q ads = 106.997 mg/g for S 2 and Q ads = 122.108 mg/g for S 1 . As a result, zeolite is an eco-friendly material that is a potential usage option, with many benefits, such as low prices, stability, and ease of regeneration and use. |
