Reinforcing 2D Single-Crystal Bi 2 O 2 CO 3 with Additional Interlayer Carbonates by CO 2 -Assisted Solid-to-Solid Phase Transition.

Autor: Yang B; College of Materials Science and Engineering, Fuzhou University, New Campus, Minhou, Fujian, 350108, China.; Key Laboratory of Advanced Materials Technologies, Fuzhou University, Fuzhou, 350108, China., Dong W; College of Materials Science and Engineering, Fuzhou University, New Campus, Minhou, Fujian, 350108, China.; Key Laboratory of Advanced Materials Technologies, Fuzhou University, Fuzhou, 350108, China., Zhu C; AQUA Worth (Suzhou) Environmental Protection Co.,Ltd, Suzhou, 215011, China., Huang X; College of Materials Science and Engineering, Fuzhou University, New Campus, Minhou, Fujian, 350108, China.; Key Laboratory of Advanced Materials Technologies, Fuzhou University, Fuzhou, 350108, China., Han Y; College of Materials Science and Engineering, Fuzhou University, New Campus, Minhou, Fujian, 350108, China.; Key Laboratory of Advanced Materials Technologies, Fuzhou University, Fuzhou, 350108, China., Zheng Y; College of Materials Science and Engineering, Fuzhou University, New Campus, Minhou, Fujian, 350108, China.; Key Laboratory of Advanced Materials Technologies, Fuzhou University, Fuzhou, 350108, China., Yan J; College of Materials Science and Engineering, Fuzhou University, New Campus, Minhou, Fujian, 350108, China.; Key Laboratory of Advanced Materials Technologies, Fuzhou University, Fuzhou, 350108, China., Zhuang Z; College of Materials Science and Engineering, Fuzhou University, New Campus, Minhou, Fujian, 350108, China.; Key Laboratory of Advanced Materials Technologies, Fuzhou University, Fuzhou, 350108, China., Yu Y; College of Materials Science and Engineering, Fuzhou University, New Campus, Minhou, Fujian, 350108, China.; Key Laboratory of Advanced Materials Technologies, Fuzhou University, Fuzhou, 350108, China.
Jazyk: angličtina
Zdroj: Small (Weinheim an der Bergstrasse, Germany) [Small] 2024 Aug; Vol. 20 (35), pp. e2401559. Date of Electronic Publication: 2024 Apr 25.
DOI: 10.1002/smll.202401559
Abstrakt: A facile gaseous CO 2 mediated solid-to-solid transformation principle is adopted to insert additional CO 3 2- anions into the thin single-crystal nanosheets of Bi 2 O 2 CO 3 , which is built of periodic arrays of intrinsic CO 3 2- anions and (Bi 2 O 2 ) 2+ layers. The additional CO 3 2- anions create abundant defects. The Bi 2 O 2 CO 3 nanosheets with rich interlayer CO 3 2- exhibit superior electronic properties and charge transfer kinetics than the pristine single-crystal 2D Bi 2 O 2 CO 3 and display enhanced catalytic activity in photocatalytic CO 2 reduction reaction and the photocatalytic oxidative degradation of organic pollutants. This work thus illustrates interlayer engineering as a flexible means to build layered 2D materials with excellent properties.
(© 2024 Wiley‐VCH GmbH.)
Databáze: MEDLINE
Externí odkaz: