Dispersive micro-solid phase extraction (D-μSPE) of nickel on activated nanodiamonds@Bi 2 WO 6 nanocomposite from water and food samples.

Autor: Soylak M; Erciyes University, Faculty of Sciences, Department of Chemistry, 38039 Kayseri, Turkey; Technology Research & Application Center (ERU-TAUM), Erciyes University, 38039 Kayseri, Turkey; Turkish Academy of Sciences (TUBA), Cankaya, Ankara, Turkey. Electronic address: soylak@erciyes.edu.tr., Ahmed HEH; Erciyes University, Faculty of Sciences, Department of Chemistry, 38039 Kayseri, Turkey; Technology Research & Application Center (ERU-TAUM), Erciyes University, 38039 Kayseri, Turkey; Sudan Atomic Energy Commission (SAEC) - Chemistry and Nuclear Physics Institute, Khartoum, Sudan; Sudan University of Science and Technology (SUST) - College of Science-Scientific Laboratories Department, Chemistry Section, Khartoum, Sudan., Goktas O; Erciyes University, Faculty of Sciences, Department of Chemistry, 38039 Kayseri, Turkey; Technology Research & Application Center (ERU-TAUM), Erciyes University, 38039 Kayseri, Turkey.
Jazyk: angličtina
Zdroj: Food chemistry [Food Chem] 2024 Aug 30; Vol. 450, pp. 139351. Date of Electronic Publication: 2024 Apr 15.
DOI: 10.1016/j.foodchem.2024.139351
Abstrakt: This study presents an original nano-sorbent using activated nanodiamonds@Bi 2 WO 6 to separate and enrich nickel ions from water and food samples. FTIR, XRD, FE-SEM, FE-SEM-EDX, EDS-TEAM, TGA, and BET were used to characterize the nanocomposite. It has a large surface area, active functional groups, and better reactivity. Ni(II) ions were determined as Ni(II)-PADAP chelates using UV-VIS spectroscopy. The parameters were studied and optimized, including pH (6), eluent type and volume (1 mL), ligand quantity (10 μg), sorbent dosage (20 mg), and contact time (1 min). The method has a low limit of detection (LOD) of 1.6 μg L -1 , a limit of quantification (LOQ) of 5.3 μg L -1 , a relative standard deviation of 4.5%, and a preconcentration factor of 10. The method was validated by applying to certified reference materials (BCR estuarine water 505 and 1573a NIST). The method was successfully applied to tap waters, industrial waste waters, and vegetables.
Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
(Copyright © 2024 Elsevier Ltd. All rights reserved.)
Databáze: MEDLINE
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