| Autor: |
Barrios LA; Departament de Química Inorgànica i Orgànica and IN2UB, Universitat de Barcelona, Diagonal 645, 08028 Barcelona, Spain. aromi@ub.edu., Capó N; Departament de Química Inorgànica i Orgànica and IN2UB, Universitat de Barcelona, Diagonal 645, 08028 Barcelona, Spain. aromi@ub.edu., Boulehjour H; Donostia International Physics Center (DIPC), Donostia, 20018, Spain., Reta D; Faculty of Chemistry, The University of the Basque Country UPV/EHU, Donostia, 20018, Spain.; Donostia International Physics Center (DIPC), Donostia, 20018, Spain.; IKERBASQUE, Basque Foundation for Science, Bilbao, 48013, Spain., Tejedor I; Instituto de Nanociencia y Materiales de Aragón (INMA), CSIC and Universidad de Zaragoza, Plaza San Francisco s/n, 50009, Zaragoza, Spain., Roubeau O; Instituto de Nanociencia y Materiales de Aragón (INMA), CSIC and Universidad de Zaragoza, Plaza San Francisco s/n, 50009, Zaragoza, Spain., Aromí G; Departament de Química Inorgànica i Orgànica and IN2UB, Universitat de Barcelona, Diagonal 645, 08028 Barcelona, Spain. aromi@ub.edu. |
| Abstrakt: |
Coordination supramolecular chemistry provides a versatile entry into materials with functionalities of technological relevance at the nanoscale. Here, we describe how two different bis-pyrazolylpyridine ligands (L1 and L2) assemble with Co(II) ions into dinuclear triple-stranded helicates, in turn, encapsulating different anionic guests. These constructs are described as (Cl@[Co 2 (L1) 3 ]) 3+ , (SiF 6 @[Co 2 (L1)(L2) 3 ]) 2+ and (ClO 4 @[Co 2 (L2) 3 ]) 3+ , as established by single-crystal X-ray diffraction. Extensive magnetic and calorimetric measurements, numerical treatments and theoretical calculations reveal that the individual Co(II) centers of these supramolecular entities exhibit field-induced slow relaxation of magnetization, dominated by direct and Raman mechanisms. While the small variations in the spin dynamics are not easily correlated with the evident structural differences among the three species, the specific heat measurements suggest two vibronic pathways of magnetic relaxation: one that would be associated with the host lattice and another linked with the guest. |
