Advanced Electroanalysis for Electrosynthesis.

Autor: Brachi M; Department of Chemistry, University of Utah, Salt Lake City, Utah 84112 United States., El Housseini W; Department of Chemistry, University of Utah, Salt Lake City, Utah 84112 United States., Beaver K; Department of Chemistry, University of Utah, Salt Lake City, Utah 84112 United States., Jadhav R; Department of Chemistry, University of Utah, Salt Lake City, Utah 84112 United States., Dantanarayana A; Department of Chemistry, University of Utah, Salt Lake City, Utah 84112 United States., Boucher DG; Department of Chemistry, University of Utah, Salt Lake City, Utah 84112 United States., Minteer SD; Department of Chemistry, University of Utah, Salt Lake City, Utah 84112 United States.; Kummer Institute Center for Resource Sustainability, Missouri University of Science and Technology, Rolla, Missouri 65409, United States.
Jazyk: angličtina
Zdroj: ACS organic & inorganic Au [ACS Org Inorg Au] 2023 Nov 29; Vol. 4 (2), pp. 141-187. Date of Electronic Publication: 2023 Nov 29 (Print Publication: 2024).
DOI: 10.1021/acsorginorgau.3c00051
Abstrakt: Electrosynthesis is a popular, environmentally friendly substitute for conventional organic methods. It involves using charge transfer to stimulate chemical reactions through the application of a potential or current between two electrodes. In addition to electrode materials and the type of reactor employed, the strategies for controlling potential and current have an impact on the yields, product distribution, and reaction mechanism. In this Review, recent advances related to electroanalysis applied in electrosynthesis were discussed. The first part of this study acts as a guide that emphasizes the foundations of electrosynthesis. These essentials include instrumentation, electrode selection, cell design, and electrosynthesis methodologies. Then, advances in electroanalytical techniques applied in organic, enzymatic, and microbial electrosynthesis are illustrated with specific cases studied in recent literature. To conclude, a discussion of future possibilities that intend to advance the academic and industrial areas is presented.
Competing Interests: The authors declare no competing financial interest.
(© 2023 The Authors. Published by American Chemical Society.)
Databáze: MEDLINE