Crystal structure and Hirshfeld surface analysis of 8-benzyl-1-[(4-methyl-phen-yl)sulfon-yl]-2,7,8,9-tetra-hydro-1 H -3,6:10,13-diep-oxy-1,8-benzodi-aza-cyclo-penta-decine ethanol hemisolvate.

Autor: Burkin GM; RUDN University, 6 Miklukho-Maklaya St., Moscow 117198, Russian Federation., Kvyatkovskaya EA; RUDN University, 6 Miklukho-Maklaya St., Moscow 117198, Russian Federation., Khrustalev VN; RUDN University, 6 Miklukho-Maklaya St., Moscow 117198, Russian Federation.; Zelinsky Institute of Organic Chemistry of RAS, 4, 7 Leninsky Prospect, 119991 Moscow, Russian Federation., Hasanov KI; Western Caspian University, Istiqlaliyyat Street 31, AZ1001, Baku, Azerbaijan.; Azerbaijan Medical University, Scientific Research Centre (SRC), A. Kasumzade St. 14. Baku, AZ 1022, Azerbaijan., Sadikhova ND; Department of Chemistry, Baku State University, Z. Xalilov Str. 23, Az 1148 Baku, Azerbaijan., Akkurt M; Department of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, Türkiye., Bhattarai A; Department of Chemistry, M.M.A.M.C (Tribhuvan University), Biratnagar, Nepal.
Jazyk: angličtina
Zdroj: Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2024 Mar 26; Vol. 80 (Pt 4), pp. 418-422. Date of Electronic Publication: 2024 Mar 26 (Print Publication: 2024).
DOI: 10.1107/S2056989024002275
Abstrakt: The asymmetric unit of the title compound, 2C 31 H 28 N 2 O 4 S·C 2 H 6 O, contains a parent mol-ecule and a half mol-ecule of ethanol solvent. The main compound stabilizes its mol-ecular conformation by forming a ring with an R 1 2 (7) motif with the ethanol solvent mol-ecule. In the crystal, mol-ecules are connected by C-H⋯O and O-H⋯O hydrogen bonds, forming a three-dimensional network. In addition, C-H⋯π inter-actions also strengthen the mol-ecular packing.
(© Burkin et al. 2024.)
Databáze: MEDLINE
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