Carbon-Supported Ru-Ni and Ru-W Catalysts for the Transformation of Hydroxyacetone and Saccharides into Glycol-Derived Primary Amines.

Autor: Boulos J; Univ. Lille, CNRS, Centrale Lille, Univ. Artois, Unité de Catalyse et de Chimie du Solide, UMR 8181, 59000, Lille, France., Goc F; Univ Lyon 1, CNRS, Institut de Recherches sur la Catalyse et l'Environnement de Lyon, UMR 5256, 2 avenue Albert Einstein, 69626, Villeurbanne, France., Vandenbrouck T; Univ Lyon 1, CNRS, Institut de Recherches sur la Catalyse et l'Environnement de Lyon, UMR 5256, 2 avenue Albert Einstein, 69626, Villeurbanne, France., Perret N; Univ Lyon 1, CNRS, Institut de Recherches sur la Catalyse et l'Environnement de Lyon, UMR 5256, 2 avenue Albert Einstein, 69626, Villeurbanne, France., Dhainaut J; Univ. Lille, CNRS, Centrale Lille, Univ. Artois, Unité de Catalyse et de Chimie du Solide, UMR 8181, 59000, Lille, France., Royer S; Univ. Lille, CNRS, Centrale Lille, Univ. Artois, Unité de Catalyse et de Chimie du Solide, UMR 8181, 59000, Lille, France., Rataboul F; Univ Lyon 1, CNRS, Institut de Recherches sur la Catalyse et l'Environnement de Lyon, UMR 5256, 2 avenue Albert Einstein, 69626, Villeurbanne, France.
Jazyk: angličtina
Zdroj: ChemSusChem [ChemSusChem] 2024 Jun 10; Vol. 17 (11), pp. e202400540. Date of Electronic Publication: 2024 May 03.
DOI: 10.1002/cssc.202400540
Abstrakt: Nitrogen-containing molecules are used for the synthesis of polymers, surfactants, agrochemicals, and dyes. In the context of green chemistry, it is important to form such compounds from bioresource. Short-chain primary amines are of interest for the polymer industry, like 2-aminopropanol, 1-aminopropan-2-ol, and 1,2-diaminopropane. These amines can be formed through the amination of oxygenated substrates, preferably in aqueous phase. This is possible with heterogeneous catalysts, however, effective systems that allow reactions under mild conditions are lacking. We report an efficient catalyst Ru-Ni/AC for the reductive amination of hydroxyacetone into 2-aminopropanol. The catalyst has been reused during 3 cycles demonstrating a good stability. As a prospective study, extension to the reactivity of (poly)carbohydrates has been realized. Despite a lesser efficiency, 2-aminopropanol (9 % yield of amines) has been formed from fructose, the first example from a carbohydrate. This was possible using a 7.5 %Ru-36 %W x C/AC catalyst, composition allowing a one-pot retro-aldol cleavage into hydroxyacetone and reductive amination. The transformation of cellulose through sequential reactions with a combination of 30 %W 2 C/AC and 7.5 %Ru-36 %W x C/AC system gave 2 % of 2-aminopropanol, corresponding to the first example of the formation of this amine from cellulose with heterogeneous catalysts.
(© 2024 Wiley-VCH GmbH.)
Databáze: MEDLINE
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